Alpha-pinene

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Names

[ CAS No. ]:
80-56-8

[ Name ]:
Alpha-pinene

[Synonym ]:
α-PINENE, (+)-
EINECS 201-291-9
Pina-2-ene
PC500
L46 A EUTJ A1 A1 D1 &&(+)-α or (1R,5R)- Form
AciteneA
(1R)-(+)-α-Pinene
1R-(+)-α-pinene
PERMOUNT
(1R,5R)-2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene
MFCD00212495
Australene
Bicyclo(3.1.1)hept-2-ene, 2,6,6-trimethyl-, (1R,5R)-
α-Pinene
2-Pinene
Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl-, (1R,5R)-
(1R,5R)-α-pinene
pin-2-ene
(1R,5R)-2-Pinene
Alpha-Pinene
Pinene
c 500

Chemical & Physical Properties

[ Density]:
0.858

[ Boiling Point ]:
154-157 ºC

[ Melting Point ]:
-55°C

[ Molecular Formula ]:
C10H16

[ Molecular Weight ]:
136.234

[ Flash Point ]:
38 ºC

[ Exact Mass ]:
136.125198

[ LogP ]:
4.37

[ Vapour Pressure ]:
3.5±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.465-1.467

[ Stability ]:
Stable. Flammable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
insoluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DT7000000
CHEMICAL NAME :
Bicyclo(3.1.1)hept-2-ene, 2,6,6-trimethyl-
CAS REGISTRY NUMBER :
80-56-8
BEILSTEIN REFERENCE NO. :
3194807
LAST UPDATED :
199712
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C10-H16
MOLECULAR WEIGHT :
136.26
WISWESSER LINE NOTATION :
L46 A EUTJ A1 A1 E1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Human - man
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3700 mg/kg
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - other changes
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
625 ug/m3
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,232,1952
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
572 ug/m3
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M4022 No. of Facilities: 214 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 815 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M4022 No. of Facilities: 7593 (estimated) No. of Industries: 92 No. of Occupations: 72 No. of Employees: 153143 (estimated) No. of Female Employees: 47130 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H304-H315-H317

[ Precautionary Statements ]:
P280-P301 + P310-P331

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R10;R36/37/38;R51/53;R65

[ Safety Phrases ]:
S26-S36/37-S61-S37/39-S29-S16

[ RIDADR ]:
UN 2368 3/PG 3

[ WGK Germany ]:
1

[ RTECS ]:
DT7000000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2902191000

Synthetic Route

Precursor & DownStream

Precursor

  • Beta-pinene
  • Cyclobutaneacetaldehyde, 3-acetyl-2,2-dimethyl-
  • carbon monoxide
  • tetra(isopinocampheyl)diborane(6)
  • Geranyl pyrophosphate
  • dimethylallyl pyrophosphate
  • (±)-Myrtenol
  • GERANYL PYROPHOSPHATE AMMONIUM 200
  • (+)-Limonene

DownStream

  • 1,3-Cyclohexadiene,1,3,5,5-tetramethyl-
  • (Z)-3,7-dimethylocta-1,3,6,-triene
  • 1,5,5,6-tetramethylcyclohexa-1,3-diene
  • limonene
  • 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one
  • Cyclohexane,1,1,2,3-tetramethyl-
  • beta-terpinene
  • o-Cymene
  • Terpinolene
  • 1-methyl-2-propan-2-ylcyclohexane

Customs

[ HS Code ]: 2902191000

[ Summary ]:
2902191000 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。Lowest tariff:2.0%。General tariff:30.0%

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Related Compounds

  • alpha-pinene
  • (+)-alpha-Pinene
  • (-)-alpha-pinene
  • POLY-ALPHA-PINENE
  • Alpha-Pinene Oxide
  • alpha-Pinene oxide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 3-(2-Methoxyphenyl)-1-methyl-1,4,7-triazaspiro[4.4]non-3-en-2-one
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 2-[(2-Methoxyethyl)amino]pyrimidine-4-carbonitrile
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine