Diafenthiuron

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Names

[ CAS No. ]:
80060-09-9

[ Name ]:
Diafenthiuron

[Synonym ]:
Thiourea, N-[2,6-bis(1-methylethyl)-4-phenoxyphenyl]-N'-(1,1-dimethylethyl)-
Diafenthiuron
1-tert-Butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea
N-tert-butyl-N’-[2,6-di(propan-2-yl)-4-phenoxyphenyl]carbonothioic diamide
PoLO
1-(2,6-Diisopropyl-4-phenoxyphenyl)-3-(2-methyl-2-propanyl)thiourea
1-tert-butyl-3-[4-phenoxy-2,6-di(propan-2-yl)phenyl]thiourea
Pegasus
N-[2,6-bis(1-methylethyl)-4-phenoxyphenyl]-N’-(1,1-dimethylethyl)thiourea
N-[2,6-Bis(1-methylethyl)-4-phenoxyphenyl]-N'-(1,1-dimethylethyl)thiourea
MFCD01311814
1-tert-Butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thioharnstoff

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
448.8±55.0 °C at 760 mmHg

[ Melting Point ]:
144.6-147.7°C

[ Molecular Formula ]:
C23H32N2OS

[ Molecular Weight ]:
384.578

[ Flash Point ]:
225.2±31.5 °C

[ Exact Mass ]:
384.223541

[ PSA ]:
65.38000

[ LogP ]:
6.00

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.582

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XN9100000
CHEMICAL NAME :
Thiourea, N-(2,6-bis(1-methylethyl)-4-phenoxyphenyl)-N'-(1,1-di methylethyl)-
CAS REGISTRY NUMBER :
80060-09-9
LAST UPDATED :
199710
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C23-H32-N2-O-S
MOLECULAR WEIGHT :
384.63

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2068 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,240,1991
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
558 mg/m3/14H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,240,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,240,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
>1500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,240,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
>1500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,240,1991

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H332

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20

[ Safety Phrases ]:
S22

[ RIDADR ]:
UN 2811

[ RTECS ]:
XN9100000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2930909053

Synthetic Route

Precursor & DownStream

Precursor

  • DIPPI

DownStream

Customs

[ HS Code ]: 2930909053

[ Summary ]:
2930909053 s-(4-phenoxybutyl) dimethylcarbamothioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

Articles

Multi-residue method for determination of 238 pesticides in Chinese cabbage and cucumber by liquid chromatography-tandem mass spectrometry: comparison of different purification procedures.

J. Agric. Food Chem. 62(47) , 11449-56, (2014)

This paper describes the comparison of five sample cleanup procedures for the determination of 238 pesticides via triple quadrupole liquid chromatography-tandem mass spectrometry (LC-MS/MS, with only ...

Diafenthiuron residue and decline in pakchoi and soil under field application.

Ecotoxicol. Environ. Saf. 79 , 75-9, (2012)

A simple analytical method based on QuEChERs was established for diafenthiuron residues in packhoi and soil. The residue levels and diaaipation rates of diafenthiuron in packhoi and soil were detected...

Field efficacy and baseline toxicities of pyriproxifen, acetamiprid, and diafenthiuron against Bemisia tabaci Gennadius (Homoptera: Aleyrodidae) in Burkina Faso (West Africa).

J. Environ. Sci. Health B 38(6) , 757-69, (2003)

Bioassays were conducted in 2001 and 2002 to estimate toxicities and dose-response relationships of 24 Bemisica tabaci Gennadius populations to pyriproxifen, acemitaprid, and diafenthiuron. LC50s rang...


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Related Compounds

  • Diafenthiuron methaneimidamide