Triisopropylsilyl trifluoromethanesulfonate

Names

[ Name ]:
Triisopropylsilyl trifluoromethanesulfonate

[Synonym ]:
tri(propan-2-yl)silyl trifluoromethanesulfonate
MFCD00009913
Triisopropylsilyl trifluoromethanesulfonate
Methanesulfonic acid, 1,1,1-trifluoro-, tris(1-methylethyl)silyl ester

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
252.9±35.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₂₁F₃O₃SSi

[ Molecular Weight ]:
306.418

[ Flash Point ]:
106.8±25.9 °C

[ Exact Mass ]:
306.093262

[ PSA ]:
51.75000

[ LogP ]:
5.17

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.410

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Triisopropylsilane
Trifluoromethanesulfonic acid
Allyl(triisopropyl)silane
Chloro(triisopropyl)silane

DownStream

2-cyclohexylethynoxy-tri(propan-2-yl)silane
1-(Triisopropylsilyloxy)cyclopropylcarboxylic Acid Methyl Ester
4-Bromophenoxytriisopropylsilane
(5-methylfuran-2-yl)oxy-tri(propan-2-yl)silane
1-tert-butylsulfanylethenoxy-tri(propan-2-yl)silane
Triisopropyl(1-propyn-1-yl)silane
1H-Pyrrolo[2,3-b]pyridine, 4-chloro-1-[tris(1-methylethyl)silyl]-
5-BROMO-1-(TRIISOPROPYLSILYL)-1H-INDOLE
2-diazonio-1-methoxy-2-tri(propan-2-yl)silylethenolate
but-3-ynoxy-tri(propan-2-yl)silane

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Greene, T.W. Wuts, P.G.M.

Protective Groups in Organic Synthesis 2nd ed., New York , (1991), 74

Synlett , 435, (1993)

Tetrahedron 62 , 11371, (2006)

triisopropylsilyl 4-(pyridine-2-yldisulfanyl)pentanoate
triisopropylsilyl p-toluate
triisopropylsilyl 4-methoxybenzoate
triisopropylsilyl 3-phenylacrylate
(triisopropylsilyl)ethenone
Triisopropylsilyl methacrylate
3-(2-Chlorophenyl)-5-[1-(3-methylbenzoyl)pyrrolidin-2-yl]-1,2,4-oxadiazole
[2-[3-(2-Chlorophenyl)-1,2,4-oxadiazol-5-yl]pyrrolidin-1-yl]-phenylmethanone
[2-[3-(2-Chlorophenyl)-1,2,4-oxadiazol-5-yl]pyrrolidin-1-yl]-(3,4-dimethylphenyl)methanone
3-(2-Chlorophenyl)-5-{1-[(4-methylphenyl)acetyl]pyrrolidin-2-yl}-1,2,4-oxadiazole
3-(2-Chlorophenyl)-5-[1-(4-isopropylbenzoyl)pyrrolidin-2-yl]-1,2,4-oxadiazole
[2-[3-(2-Chlorophenyl)-1,2,4-oxadiazol-5-yl]pyrrolidin-1-yl]-(4-ethoxyphenyl)methanone
3-(2-Chlorophenyl)-5-{1-[(2-methylphenyl)acetyl]pyrrolidin-2-yl}-1,2,4-oxadiazole
3-(2-Chlorophenyl)-5-[1-(3-phenylpropanoyl)pyrrolidin-2-yl]-1,2,4-oxadiazole
Methyl 3-({2-[3-(2-chlorophenyl)-1,2,4-oxadiazol-5-yl]pyrrolidin-1-yl}carbonyl)benzoate
3-(2-Chlorophenyl)-5-[1-(3-fluoro-4-methoxybenzoyl)pyrrolidin-2-yl]-1,2,4-oxadiazole

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