nitro m-xylene

Suppliers

Names

[ CAS No. ]:
81-20-9

[ Name ]:
nitro m-xylene

[Synonym ]:
2,6-dimethyl nitrobenzene
2-Nitro-m-xylene
1,3-Dimethyl-2-nitrobenzene
MFCD00007181
Benzene, 1,3-dimethyl-2-nitro-
nitro m-xylene
EINECS 201-333-6

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
224.4±9.0 °C at 760 mmHg

[ Melting Point ]:
14-16 °C(lit.)

[ Molecular Formula ]:
C8H9NO2

[ Molecular Weight ]:
151.163

[ Flash Point ]:
87.8±0.0 °C

[ Exact Mass ]:
151.063324

[ PSA ]:
45.82000

[ LogP ]:
2.87

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.547

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZE4686000
CHEMICAL NAME :
m-Xylene, 2-nitro-
CAS REGISTRY NUMBER :
81-20-9
BEILSTEIN REFERENCE NO. :
2046066
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C8-H9-N-O2
MOLECULAR WEIGHT :
151.18
WISWESSER LINE NOTATION :
WNR B1 F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
45 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00236

Safety Information

[ Symbol ]:

GHS09

[ Hazard Statements ]:
H411

[ Precautionary Statements ]:
P273

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xn:Harmful;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R20/21;R51/53

[ Safety Phrases ]:
S61-S36/37-S36-S26-S16

[ RIDADR ]:
UN 1665 6.1/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
ZE4686000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
29042000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,6-xylidine
  • 3,5-Dimethylphenylboronic acid
  • m-Xylene
  • 1,2,4,5-Tetramethylbenzene
  • 1-(3,5-dimethyl-4-nitrophenyl)-2-(phenylthio)diazene
  • Tetrabutylammonium cyanide
  • Benzene,2,4-dimethyl-1,3,5-trinitro-
  • 2,4-Dimethyl-3-nitroaniline
  • 4,6-dimethyl-5-nitrobenzene-1,3-diamine
  • 2,4-Xylidine

DownStream

  • 4-Nitro-m-xylene
  • 7-Methyl-2,1-benzoxazole
  • Dimethyl 2-Nitroisophthalate
  • 3-Methyl-2-nitrobenzoic acid
  • 2,4-dinitro-m-xylene
  • 2-aminoisophthalicacid
  • 2,6-xylidine
  • N-ethyl-2,6-dimethylaniline
  • N,N-diethyl-2,6-dimethylaniline
  • bis-(2,6-dimethyl-phenyl)-diazene-N-oxide

Customs

[ HS Code ]: 2904209090

[ Summary ]:
2904209090 derivatives containing only nitro or only nitroso groups。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

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Macromol. Biosci. 15 , 1314-22, (2015)

We designed poly(β-amino esters) (PBAEs) bearing both UV light- and pH-sensitive groups and used PBAEs to prepare nanoparticles (NPs) that can be utilized for on-demand burst release of guest molecule...


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Related Compounds

  • 4-Nitro-m-xylene
  • Acetamide,N-(2,4-dimethyl-6-nitrophenyl)-
  • 1-BROMO-2,4-DIMETHYL-5-NITROBENZENE
  • 2,6-Dimethyl-4-nitroanisole
  • (η6-m-xylene)tricarbonylchromium(0)
  • Sulfone, methyl 4-nitro-2,6-xylyl (5CI)
  • 9,9-dimethyl-N-(4-phenylphenyl)fluoren-4-amine
  • 7-(1-Methylpyrazol-4-yl)-1,5-naphthyridin-2-amine
  • 3-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazol-1-yl]propyl acetate
  • (3-Cyclopropoxy-5-(methylthio)pyridin-4-YL)methanamine
  • N-(1-isobutyl-1H-indol-4-yl)-2-methylpropanamide
  • 2-(6,7-dimethoxy-2-methyl-4-oxoquinazolin-3(4H)-yl)-N-(1-methyl-1H-indol-4-yl)acetamide
  • 4-(Aminomethyl)-5-cyclopropoxypicolinamide
  • 2-{[(Tert-butoxy)carbonyl]amino}-3-(1-methylcyclohexyl)propanoic acid
  • 3-(3,5-dimethyl-1H-pyrazol-4-yl)-1-(1,3,4,9-tetrahydro-2H-beta-carbolin-2-yl)-1-propanone
  • 4-(Aminomethyl)-5-cyclopropoxypicolinic acid
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