Dimethyl chlorophosphate

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Names

[ CAS No. ]:
813-77-4

[ Name ]:
Dimethyl chlorophosphate

[Synonym ]:
[chloro(methoxy)phosphoryl]oxymethane
MFCD00117904

Chemical & Physical Properties

[ Density]:
1.34 g/mL at 25ºC(lit.)

[ Boiling Point ]:
80ºC25 mm Hg(lit.)

[ Molecular Formula ]:
C2H6ClO3P

[ Molecular Weight ]:
144.49400

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
143.97400

[ PSA ]:
45.34000

[ LogP ]:
1.62610

[ Index of Refraction ]:
n20/D 1.413(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300 + H310 + H330-H314

[ Precautionary Statements ]:
Missing Phrase - N15.00950417-P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338 + P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T+: Very toxic;

[ Risk Phrases ]:
R26/27/28

[ Safety Phrases ]:
26-36/37/39-45-7/9

[ RIDADR ]:
UN 2927 6

[ WGK Germany ]:
3

[ Hazard Class ]:
6.1

[ HS Code ]:
29199000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl phosphite, (MeO)2(HO)P
  • Dimethyl phosphonate
  • Methanol
  • Trimethyl phosphite
  • DIMETHYLCHLOROPHOSPHITE
  • N-chloro-N-methylsulfonylmethanesulfonamide
  • ch3cho
  • Trichloroacetonitrile
  • Carbon tetrachloride
  • Sodium Methylate

DownStream

  • Diphosphoric acid P1,P1-diethyl-P2,P2-dimethyl ester
  • Methyl paraoxon
  • (4-chlorophenyl) dimethyl phosphate
  • N-dimethoxyphosphorylpropan-1-amine
  • N-dimethoxyphosphorylbutan-1-amine
  • 9-Methylanthracene
  • Trimethyl phosphate
  • Dimethyl phosphate
  • DIMETHYLETHYLPHOSPHATE
  • (2-methoxyphenyl) dimethyl phosphate

Articles

(E)-3-Cyanophosphoenolpyruvate, a new inhibitor of phosphoenolpyruvate-dependent enzymes.

Biochemistry 24(26) , 7602-6, (1985)

(E)-3-Cyanophosphoenolpyruvate has been synthesized by reacting dimethyl chlorophosphate with the potassium enolate of ethyl cyanopyruvate. The resulting trialkyl ester was deesterified with bromotrim...

Interactions and binding energies of dimethyl methylphosphonate and dimethyl chlorophosphate with amorphous silica.

Langmuir 28(30) , 10962-7, (2012)

The fundamental interactions of dimethyl methylphosphonate (DMMP) and dimethyl chlorophosphate (DMCP) on amorphous silica nanoparticles have been investigated with transmission infrared spectroscopy a...

Synthesis, in vitro evaluation, and intraocular pressure effects of water-soluble prodrugs of endocannabinoid noladin ether.

J. Med. Chem. 46(23) , 5083-86, (2003)

The poor aqueous solubility of 2-arachidonyl glyceryl ether (noladin ether) 2 hinders both pharmacological studies and pharmaceutical development. The synthesized mono- and diphosphate esters of nolad...


More Articles

Related Compounds

  • dimethyl-bis(2-methylpropyl)azanium,iodide
  • dimethyl(dipentyl)azanium,bromide
  • [dimethyl(phenyl)-λ5-arsanyl] thiohypobromite
  • [dimethyl(phenyl)-λ5-arsanyl] thiohypochlorite
  • dimethyl glutarate
  • Dimethyl 3-hydroxypentanedioate
  • 3-amino-1-(1-phenyl-1H-pyrazol-4-yl)cyclobutane-1-carboxylic acid
  • 3-Amino-1-{4-[(difluoromethyl)sulfanyl]phenyl}cyclobutane-1-carboxylic acid
  • 2-Amino-3-hydroxy-3-(3-hydroxy-4-nitrophenyl)propanoic acid
  • 3-Amino-1-[3-fluoro-5-(trifluoromethyl)phenyl]cyclobutane-1-carboxylic acid
  • 4-amino-4-[3,5-dimethyl-1-(propan-2-yl)-1H-pyrazol-4-yl]butanoic acid
  • 3-Amino-1-[2-methoxy-3-(trifluoromethyl)phenyl]cyclobutane-1-carboxylic acid
  • 3-Amino-1-(3-hydroxy-4-methoxyphenyl)cyclobutane-1-carboxylic acid
  • 2-Amino-2-[1-(2-methoxy-6-methylphenyl)cyclopropyl]acetic acid
  • 3-amino-3-(1-ethenyl-1H-pyrazol-4-yl)propanoic acid
  • 2-Amino-3-(3-chloro-4-nitrophenyl)propanoic acid
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