Acrylyl chloride

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Names

[ CAS No. ]:
814-68-6

[ Name ]:
Acrylyl chloride

[Synonym ]:
2-Propenoyl chloride
prop-2-enoyl chloride
Prop-2-enoylchlorid
MFCD00000731
PROPENOYL CHLORIDE
EINECS 212-399-0
Acryloyl chloride

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
75.5±0.0 °C at 760 mmHg

[ Melting Point ]:
72-76ºC

[ Molecular Formula ]:
C3H3ClO

[ Molecular Weight ]:
90.508

[ Flash Point ]:
16.1±0.0 °C

[ Exact Mass ]:
89.987244

[ PSA ]:
17.07000

[ LogP ]:
1.06

[ Vapour density ]:
>1 (vs air)

[ Vapour Pressure ]:
104.8±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.417

[ Stability ]:
Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AT7350000
CHEMICAL NAME :
Acryloyl chloride
CAS REGISTRY NUMBER :
814-68-6
BEILSTEIN REFERENCE NO. :
0635744
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C3-H3-Cl-O
MOLECULAR WEIGHT :
90.51
WISWESSER LINE NOTATION :
GV1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
25 ppm/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - iritis Behavioral - ataxia Lungs, Thorax, or Respiration - emphysema
REFERENCE :
BJIMAG British Journal of Industrial Medicine. (British Medical Journal, Box 560B, Kennebunkport, ME 04046) V.1- 1944- Volume(issue)/page/year: 27,1,1970
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
92 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,17,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03367 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3;Skin JAN 1993

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H314-H330

[ Precautionary Statements ]:
P210-P260-P280-P284-P305 + P351 + P338-P310

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R11;R34

[ Safety Phrases ]:
S16-S26-S28-S36/37/39-S45-S7/9

[ RIDADR ]:
UN 3383 6.1/PG 1

[ WGK Germany ]:
3

[ RTECS ]:
AT7350000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2916190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Acrylic acid
  • 3-Bromopropanoyl chloride
  • phosgene
  • Benzoyl chloride
  • 3-Chloropropanoyl chloride
  • acrolein
  • Sodium acrylate

DownStream

  • naphthalen-2-yl prop-2-enoate
  • naphthalen-2-yl 3-chloropropanoate
  • 12-bromododecyl prop-2-enoate
  • d-menthyl acrylate
  • 4,4-dimethyl-3-prop-2-enoyl-1,3-oxazolidin-2-one
  • 1h,1h-perfluorooctyl acrylate
  • N-acryloxysuccinimide
  • 1H,1H-PERFLUORO-N-DECYL ACRYLATE
  • Diethylene glycol diacrylate
  • Ethyl 3-(diethoxyphosphoryl)propanoate

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

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