METHYL (S)-(+)-3-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-CIS-2-PROPENOATE

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Names

[ CAS No. ]:
81703-94-8

[ Name ]:
METHYL (S)-(+)-3-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-CIS-2-PROPENOATE

[Synonym ]:
(4S)-methyl 3-(2,2-dimethyl-1,3-dioxolan-4-yl)acrylate
METHYL 3-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-2-PROPENOATE
methyl (2Z)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]acrylate
methyl (S)-(2,2-dimethyl-1,3-dioxolane-4-yl)-cis-2-propenoate
MFCD00075399
cis-(S)-3-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-propenoate
(S,Z)-methyl 3-(2,2-dimethyl-1,3-dioxolan-4-yl)acrylate
methyl (2Z,4'S)-3-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)-2-propenoate
2-Propenoic acid,3-(2,2-dimethyl-1,3-dioxolan-4-yl)-,methyl ester
Methyl (4S)-(Z)-4,5-isopropylidenedioxypent-2-enoate

Chemical & Physical Properties

[ Density]:
1.067 g/mL at 25ºC(lit.)

[ Boiling Point ]:
60-62ºC0.2 mm Hg(lit.)

[ Molecular Formula ]:
C9H14O4

[ Molecular Weight ]:
186.20500

[ Flash Point ]:
204 °F

[ Exact Mass ]:
186.08900

[ PSA ]:
44.76000

[ LogP ]:
0.86710

[ Index of Refraction ]:
n20/D 1.449(lit.)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde
  • (s)-4,5-isopropylidene-2-pentenol
  • Ethanoic anhydride
  • 1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol
  • Methyl 2-(dimethoxyphosphoryl)acetate
  • (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide
  • (z)-ethyl-4,5-o-isopropylidene-(s)-4,5-dihydroxy-2-pentenoate
  • Methyl 2-(diethoxyphosphoryl)acetate
  • (iPrO)2P(O)CH2CO2Me

DownStream

  • (S)-5-Hydroxymethyl-2(5H)-furanone
  • [(3R,3aS,6aR)-Hydroxyhexahydrofuro[2,3-b]furanyl Succinimidyl Carbonate
  • (3R,3aS,6aR)-hexahydrofuro[2,3-b]furan-3-ol
  • METHYL5-BORONONICOTINATE
  • 2(5h)-furanone, 5-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-, (5s)- (9ci)

Related Compounds

  • 8-(Bromomethyl)-3-fluoroquinoline
  • 3-(1-Aminocyclopentyl)-1-azabicyclo[2.2.2]octan-3-ol
  • ethyl 1-methyl-4-(3-oxobut-1-en-1-yl)-1H-pyrazole-3-carboxylate
  • 9,9-Diethyl-1-methyl-4,8-dioxa-1,10-diazaspiro[5.5]undecane
  • 3-(1-Amino-2,2-difluorocyclopropyl)-2,2-dimethyl-1lambda6-thiolane-1,1-dione
  • Dispiro[2.1.5^{5}.3^{3}]tridecan-12-ylmethanamine
  • [2-(1-methyl-1H-1,2,3-triazol-5-yl)piperidin-3-yl]methanamine
  • 10-Ethyl-2,6-dioxa-14-azadispiro[3.2.6^{7}.2^{4}]pentadecane
  • 10,10-Difluoro-6-oxa-13-azadispiro[3.2.5^{7}.2^{4}]tetradecane
  • 5-Amino-1-[4-(dimethylamino)butyl]-1,2-dihydropyridin-2-one
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