2-(Bromomethyl)-1-chloro-4-fluorobenzene

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Names

[ CAS No. ]:
81778-09-8

[ Name ]:
2-(Bromomethyl)-1-chloro-4-fluorobenzene

[Synonym ]:
MFCD01631419
GR DF B1E
2-(Bromomethyl)-1-chloro-4-fluorobenzene
Benzene, 2-(bromomethyl)-1-chloro-4-fluoro-
2-Chloro-5-fluorobenzylbromide

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
223.7±25.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H5BrClF

[ Molecular Weight ]:
223.470

[ Flash Point ]:
89.1±23.2 °C

[ Exact Mass ]:
221.924713

[ LogP ]:
3.52

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.562

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H314

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;C: Corrosive;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S16-S23-S26-S33-S36/37/39-S45

[ RIDADR ]:
UN 2924 3/PG 1

[ WGK Germany ]:
3

[ Hazard Class ]:
3.0， 8.0

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Chloro-5-fluorotoluene
  • 2-chloro-5-fluorobenzyl alcohol
  • 2-Chloro-5-fluorobenzoic acid
  • Methyl 2-chloro-5-fluorobenzoate

DownStream

  • 2-Chloro-5-fluorobenzaldehyde

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

An Unusual Fluorine Atom Rearrangement in the Photocyclization of 1-Fluoro[ 5]helicenes. Mallory FB and Mallory CW.

J. Org. Chem. 48(4) , 526, (1983)


More Articles

Related Compounds

  • 2-Bromomethyl-1-chloro-4-iodo-benzene
  • 2-(bromomethyl)-1-chloro-4-phenylbenzene
  • 2-(Bromomethyl)-1-chloro-4-methoxybenzene
  • 2-(bromomethyl)-1-chloro-4-(difluoromethoxy)benzene
  • 2-(Bromomethyl)-1-chloro-4-nitrobenzene
  • 2-Chloro-5-(trifluoromethyl)benzyl bromide
  • 2-((3-(benzo[d][1,3]dioxol-5-ylmethyl)-4-oxo-3,4-dihydrothieno[3,2-d]pyrimidin-2-yl)thio)-N-ethyl-N-phenylacetamide
  • 2-((2-(3,4-dihydroquinolin-1(2H)-yl)-2-oxoethyl)thio)-3-phenethylthieno[3,2-d]pyrimidin-4(3H)-one
  • 4-[(4-oxo-2-{[2-oxo-2-(1,2,3,4-tetrahydroquinolin-1-yl)ethyl]sulfanyl}-3H,4H-thieno[3,2-d]pyrimidin-3-yl)methyl]cyclohexane-1-carboxylic acid
  • N-(3,5-dimethylphenyl)-2-((3-isobutyl-4-oxo-3,4-dihydrothieno[3,2-d]pyrimidin-2-yl)thio)acetamide
  • 5-[(Pyrrolidin-3-yl)methyl]isoquinoline
  • 2-Chloro-6-cyclopropoxy-N-methylaniline
  • 5-Cyclopropoxy-4-isopropoxy-N-methylpyridin-2-amine
  • 2-((2-fluorobenzyl)thio)-3-isobutylthieno[3,2-d]pyrimidin-4(3H)-one
  • 2-((4-fluorobenzyl)thio)-3-isobutylthieno[3,2-d]pyrimidin-4(3H)-one
  • 2-{[(2-fluorophenyl)methyl]sulfanyl}-3-(2-hydroxypropyl)-3H,4H-thieno[3,2-d]pyrimidin-4-one
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