1-Amino-2-methyl-anthraquinone

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Names

[ CAS No. ]:
82-28-0

[ Name ]:
1-Amino-2-methyl-anthraquinone

[Synonym ]:
1-Amino-2-methyl-anthraquinone
1-amino-2-methylanthracene-9,10-dione
1-Amino-2-methylanthraquinone (C.I. 60700)
MFCD00001220
EINECS 201-408-3
1-Amino-2-methyl-9,10-anthraquinone
9,10-Anthracenedione, 1-amino-2-methyl-

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
481.1±45.0 °C at 760 mmHg

[ Melting Point ]:
204-206 °C(lit.)

[ Molecular Formula ]:
C15H11NO2

[ Molecular Weight ]:
237.253

[ Flash Point ]:
244.8±28.7 °C

[ Exact Mass ]:
237.078979

[ PSA ]:
60.16000

[ LogP ]:
3.81

[ Vapour Pressure ]:
0.0±1.2 mmHg at 25°C

[ Index of Refraction ]:
1.688

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CB5740000
CHEMICAL NAME :
Anthraquinone, 1-amino-2-methyl-
CAS REGISTRY NUMBER :
82-28-0
BEILSTEIN REFERENCE NO. :
0650595
LAST UPDATED :
199701
DATA ITEMS CITED :
15
MOLECULAR FORMULA :
C15-H11-N-O2
MOLECULAR WEIGHT :
237.27
WISWESSER LINE NOTATION :
L C666 BV IVJ DZ E1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
30 gm/kg/78W-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
37 gm/kg/73W-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
60 gm/kg/78W-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
39 gm/kg/77W-C
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
307 gm/kg/73W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
557 gm/kg/79W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1113 gm/kg/79W-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - Kidney tumors

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
33 ug/plate
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 11(Suppl 12),1,1988 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 27,199,1982 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 27,199,1982 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
CB5740000

[ HS Code ]:
2922399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,3-Dichlor-1,4-naphthochinone
  • 2-Methyl-1-nitro-9,10-anthraquinone
  • Piperidine
  • 3-methyl-anthra[1,9-cd]isoxazol-6-one
  • Dibutylamine
  • Dimethylamine
  • 1-Nitroanthracene-9,10-dione
  • Diethylamine
  • Aminoform
  • 2-methyl-1-(toluene-4-sulfonylamino)-anthraquinone

DownStream

  • 1-Amino-2-methyl-4-bromoanthraquinone
  • 1-Amino-4-Chloro-2-Methylanthraquinone
  • 1-Chloro-2-methylanthraquinone
  • 2-Methyl-1-nitro-9,10-anthraquinone
  • 2,2'-Dimethyl-1,1'-bianthraquinone
  • 1-Hydroxy-2-methylanthraquinone
  • 1-(2-methyl-9,10-dioxoanthracen-1-yl)-3-phenylurea
  • 2-(bromomethyl)-1-methoxyanthracene-9,10-dione

Customs

[ HS Code ]: 2922399090

[ Summary ]:
2922399090 other amino-aldehydes, amino-ketones and amino-quinones, other than those containing more than one kind of oxygen function; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

1-Amino-2-methylanthraquinone.

IARC Monogr. Eval. Carcinog. Risk Chem. Hum. 27 , 199-204, (1982)

1-Amino-2-methylanthraquinone.

Rep. Carcinog. 12 , 41, (2011)

1-Amino-2-methylanthraquinone.

Rep. Carcinog. 11 , III16, (2004)


More Articles

Related Compounds

  • 1-amino-2-methyl-4-thiocyanato-anthraquinone
  • 1-amino-2-methyl-4-(4-tert.-butylphenylmercapto)-anthraquinone
  • 1-amino-2-methyl-4-[(4-methylphenyl)amino]anthraquinone
  • 1-Amino-2-methyl-4-bromoanthraquinone
  • 1-amino-2-(phenylimino-methyl)-anthraquinone
  • (1-amino-2-methyl-propan-2-yl)phosphonic acid
  • 7-bromo-5-(propan-2-yl)-1,5-dihydro-4H-pyrazolo[4,3-c]quinolin-4-one
  • 7-Bromo-4-chloro-2-oxo-1-(propan-2-yl)-1,2-dihydroquinoline-3-carbaldehyde
  • N-(5-chloro-4-fluoro-2-iodophenyl)-1-(tetrahydro-2H-pyran-2-yl)-1H-pyrazole-4-carboxamide
  • 3-[(4-Chloro-1,3,5-triazin-2-yl)amino]benzenemethanesulfonamide
  • 4-Chloro-N-(3-nitrophenyl)-1,3,5-triazine-2-amine
  • 2-[3-((4-Chloro-1,3,5-triazin-2-yl)amino)phenyl]ethanesulfonamide
  • 3-[(4-Chloro-1,3,5-triazin-2-yl)amino]benzamide
  • 4-[(4-Chloro-1,3,5-triazin-2-yl)amino]benzenemethanesulfonamide
  • 6-[(4-Chloro-1,3,5-triazin-2-yl)amino]-2,3-dihydro-1H-indole-1-sulfonamide
  • 4-(2-Pyridinyldithio)butanoic acid hydrazide
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