1-(Methylamino)anthraquinone

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Names

[ CAS No. ]:
82-38-2

[ Name ]:
1-(Methylamino)anthraquinone

[Synonym ]:
9,10-Anthracenedione, 1-(methylamino)-
1-(Methylamino)-9,10-anthraquinone
1-(Methylamino)anthracene-9,10-dione
9,10-Anthracenedione, 1- (methylamino)-
Disperse Red 9
MFCD00001197
1-(Methylamino)anthraquinone
Anthraquinone, 1- (methylamino)-
EINECS 201-417-2
L C666 BV IVJ DM1

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
463.2±34.0 °C at 760 mmHg

[ Melting Point ]:
170-172°C

[ Molecular Formula ]:
C15H11NO2

[ Molecular Weight ]:
237.253

[ Flash Point ]:
195.3±25.8 °C

[ Exact Mass ]:
237.078979

[ PSA ]:
46.17000

[ LogP ]:
2.76

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.691

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CB0536600
CHEMICAL NAME :
9,10-Anthracenedione, 1-(methylamino)-
CAS REGISTRY NUMBER :
82-38-2
BEILSTEIN REFERENCE NO. :
1973186
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C15-H11-N-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
>8 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 12,499,1983
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 12,499,1983 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T0958 No. of Facilities: 407 (estimated) No. of Industries: 3 No. of Occupations: 13 No. of Employees: 13258 (estimated) No. of Female Employees: 6121 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
CB0536600

Synthetic Route

Precursor & DownStream

Precursor

  • Tetrabutylammonium bromide
  • Fast Red AL
  • Dimethyl sulfate
  • Chlorobenzene
  • Trimethyl phosphite
  • 1,3-Dimethylurea
  • 1-Nitroanthracene-9,10-dione
  • 1-Fluoroanthraquinone
  • 1,1-Dimethylhydrazine
  • Acrylonitrile

DownStream

  • Fast Red AL
  • 1-Bromo-4-methylaminoanthraquinone
  • 2-methyl-N-[2-[4-(2-methylbenzoyl)piperazin-1-yl]ethyl]benzamide
  • 1-amino-4-(methylamino)anthraquinone
  • 1-iodo-4-(methylamino)anthracene-9,10-dione
  • 1-(methylamino)-10H-anthracen-9-one
  • 9,10-Anthracenedione,1-hydroxy-4-(methylamino)-

Articles

Inhalation toxicity of a smoke containing Solvent Yellow 33, Disperse Red 9 and Solvent Green 3 in laboratory animals.

Hum. Toxicol. 3(4) , 289-308, (1984)

The repeated-dose inhalation toxicity of a smoke containing a mixture of three dyes was tested in female mice, rats and guinea pigs. The green component dye (Solvent Green 3) was retained in the lungs...


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Related Compounds

  • 4-Bromo-1-(methylamino)anthraquinone
  • 1-(methylamino)-4-(phenylamino)anthraquinone
  • 1-methylamino-4-thiocyanato-anthraquinone
  • 1-methylamino-4-(4-nitrophenylamino)anthraquinone
  • 1-(Methylamino)-4-[(2-methylphenyl)amino]anthraquinone
  • 1-Methylamino-8-nitro-9,10-anthraquinone
  • N-(1,3-benzodioxol-5-yl)-2-[4,6-dimethyl-2-oxo-3-(phenylsulfonyl)pyridin-1(2H)-yl]acetamide
  • 2-[3-(benzenesulfonyl)-4,6-dimethyl-2-oxo-1,2-dihydropyridin-1-yl]-N-(3-chloro-2-methylphenyl)acetamide
  • N-(2,5-difluorophenyl)-2-(3-(3-(4-fluorophenyl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)acetamide
  • 2-(3-(3-(benzo[d][1,3]dioxol-5-yl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)-N-benzylacetamide
  • 2-(3-(3-(benzo[d][1,3]dioxol-5-yl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)-N-(2-methoxybenzyl)acetamide
  • N-(benzo[d][1,3]dioxol-5-yl)-2-(3-(3-(benzo[d][1,3]dioxol-5-yl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)acetamide
  • (3,5-dimethyl-1H-pyrazol-1-yl)(3-((4-(4-fluorophenyl)piperazin-1-yl)sulfonyl)-1H-pyrazol-5-yl)methanone
  • N-{1-[1-(4-chlorophenyl)-1H-pyrazolo[3,4-d]pyrimidin-4-yl]-3-methyl-1H-pyrazol-5-yl}-4-phenylbutanamide
  • N-{1-[1-(4-chlorophenyl)-1H-pyrazolo[3,4-d]pyrimidin-4-yl]-3-methyl-1H-pyrazol-5-yl}-3-phenylpropanamide
  • N-(1-(1-(4-chlorophenyl)-1H-pyrazolo[3,4-d]pyrimidin-4-yl)-3-methyl-1H-pyrazol-5-yl)-2,6-difluorobenzamide
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