m-methoxybenzyl chloride

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Names

[ CAS No. ]:
824-98-6

[ Name ]:
m-methoxybenzyl chloride

[Synonym ]:
m-methoxybenzyl chloride
EINECS 212-541-1
Benzene, 1-(chloromethyl)-3-methoxy-
1-(Chloromethyl)-3-methoxybenzene
Anisole, m-(chloromethyl)-
Anisole, m- (chloromethyl)-
Benzene, 1- (chloromethyl)-3-methoxy-
3-(Chloromethyl)phenyl methyl ether
MFCD00000907

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
253.9±0.0 °C at 760 mmHg

[ Melting Point ]:
101.67°C

[ Molecular Formula ]:
C8H9ClO

[ Molecular Weight ]:
156.609

[ Flash Point ]:
101.7±0.0 °C

[ Exact Mass ]:
156.034195

[ PSA ]:
9.23000

[ LogP ]:
2.40

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.517

[ Storage condition ]:
Store at?0-5°C

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
1

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29093090

Synthetic Route

Precursor & DownStream

Precursor

  • Morpholine-4-carbaldehyde
  • benzenemethanol, 3-methoxy-, 1-methansulfonate
  • 3-Methoxybenzyl alcohol
  • 1-Methoxy-3-(methoxymethyl)benzene
  • 1-(dimethoxymethyl)-3-methoxybenzene
  • m-Anisaldehyde
  • 3-Methylanisole
  • 3-methoxybenzyl tosylate
  • 3-Hydroxybenzaldehyde
  • Dimethyl sulfate

DownStream

  • 1-[(3-methoxyphenyl)methyl]pyridin-1-ium,chloride
  • Diethyl (3-methoxybenzyl)phosphonate
  • 1-methoxy-3-(3-methylbut-3-enyl)benzene
  • 1-(3-Methoxybenzyl)piperazine
  • ethyl 3-methoxyphenylacetate
  • 2-Hydroxy-3'-methoxystilbene
  • 2-(3-Methoxyphenyl)ethanol
  • Aceticacid, 2-[[(3-methoxyphenyl)methyl]thio]-
  • 1-methoxy-3-phenylmethoxy-benzene
  • m-Anisaldehyde

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

N-vs O-Alkylation in 2 (1H)-quinolinone derivatives. Guo Z-X, et al.

Tetrahedron Lett. 40(38) , 6999-7002, (1999)

Cross-couplings between benzylic and aryl halides "on water": synthesis of diarylmethanes.

Chem. Commun. (Camb.) 46(4) , 562-4, (2010)

A remarkably simple entry to unsymmetrical diarylmethanes has been developed that relies on an in situ organozinc-mediated, palladium-catalyzed cross-coupling. Thus, by mixing a benzyl and aryl halide...


More Articles


Related Compounds

  • m-methoxybenzyl N-bromo-N-methylcarbamate
  • m-methoxybenzyl diethyl phosphate
  • N-m-methoxybenzyl-S-methylisothiazolidinium chloride
  • 3-methoxybenzylmagnesium chloride
  • 2-methoxybenzylmagnesium chloride
  • 3-(chloromethyl)phenol