Phenanthrene-9,10-dione

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Names

[ CAS No. ]:
84-11-7

[ Name ]:
Phenanthrene-9,10-dione

[Synonym ]:
Phenanthrenequinone
MFCD00001163
9,10-phenanthraquinone
9,10-Phenanthrenedione
phenanthrene-9,10-dione
EINECS 201-515-5
9,10-Phenanthrenequinone

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
360.0±0.0 °C at 760 mmHg

[ Melting Point ]:
209-212 °C(lit.)

[ Molecular Formula ]:
C14H8O2

[ Molecular Weight ]:
208.212

[ Flash Point ]:
163.1±4.4 °C

[ Exact Mass ]:
208.052429

[ PSA ]:
34.14000

[ LogP ]:
3.13

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.659

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SF7875000
CHEMICAL NAME :
Phenanthrenequinone
CAS REGISTRY NUMBER :
84-11-7
BEILSTEIN REFERENCE NO. :
0608838
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C14-H8-O2
MOLECULAR WEIGHT :
208.22
WISWESSER LINE NOTATION :
L B666 HVVJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
165 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
800 mg/kg/29W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors Tumorigenic - tumors at site of application

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Bacteria - Bacillus subtilis
DOSE/DURATION :
400 ug/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 66,337,1979 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5889 No. of Facilities: 306 (estimated) No. of Industries: 4 No. of Occupations: 4 No. of Employees: 3675 (estimated) No. of Female Employees: 632 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S24/25-S22

[ RIDADR ]:
UN3077

[ WGK Germany ]:
3

[ RTECS ]:
SF7875000

[ Packaging Group ]:
III

[ Hazard Class ]:
9

[ HS Code ]:
29146990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 9-Phenanthrol
  • Phenanthrene
  • (9R,10R)-trans-9,10-dihydroxy-3,4-dihydrophenanthrene
  • 1H-Indene-1,2,3-trione
  • Methyl benzoate
  • Ethyl benzoate
  • [1,1'-Biphenyl]-2,2'-dicarboxylicacid, 2,2'-dimethyl ester
  • Benzil
  • 9 (10H)-Phenanthrone, 10-diazo-
  • 1-([1,1'-Biphenyl]-2-yl)ethanone

DownStream

  • Flurecol
  • 9-Fluorenone
  • 9-fluorenol
  • 9,9,10,10-tetrafluorophenanthrene
  • 9,10-Phenanthrenedione, dioxime
  • 9,10-Phenanthrenedione,9-oxime
  • 9-Aminophenanthrene
  • biphenyl-2,2'-dicarboxylic acid
  • 2-(2-hydroxyphenyl)benzoic acid
  • Biphenyl-2-carboxylic acid

Customs

[ HS Code ]: 2914399090

[ Summary ]:
2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Fluorescence Titrations of Bio-relevant Complexes with DNA: Synthesis, Structural Investigation, DNA Binding/Cleavage, Antimicrobial and Molecular Docking Studies.

J. Fluoresc. 25 , 1127-40, (2015)

In the present work, we attempted to develop new metal complexes (Cu(II), Co(II), Ni(II) and Zn(II)) of the imine ligand which was synthesized from 9,10-phenanthrenequinone and para-anisidine. With an...

Sulfa drugs inhibit sepiapterin reduction and chemical redox cycling by sepiapterin reductase.

J. Pharmacol. Exp. Ther. 352(3) , 529-40, (2015)

Sepiapterin reductase (SPR) catalyzes the reduction of sepiapterin to dihydrobiopterin (BH2), the precursor for tetrahydrobiopterin (BH4), a cofactor critical for nitric oxide biosynthesis and alkylgl...

3-Deoxyglucosone: a potential glycating agent accountable for structural alteration in H3 histone protein through generation of different AGEs.

PLoS ONE 10(2) , e0116804, (2015)

Advanced glycation end-products (AGEs) are heterogeneous group of compounds, known to be implicated in diabetic complications. One of the consequences of the Maillard reaction is attributed to the pro...


More Articles

Related Compounds

  • phenanthrene-9,10-dione oxime
  • 2-iodophenanthrene-9,10-dione
  • 2-bromophenanthrene-9,10-dione
  • 3-Bromophenanthrene-9,10-dione
  • 2-aminophenanthrene-9,10-dione
  • 4-nitrophenanthrene-9,10-dione
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 1-benzyl-5-(trifluoromethyl)-1H-pyrazole-4-carboxylic acid
  • 2-Sulfamoylpentanoic acid
  • 1-(3-chloro-4-methylphenyl)-3-(4-ethylphenyl)-8-fluoro-1H-pyrazolo[4,3-c]quinoline
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 3-(2,5-Dimethoxyphenyl)butanoic acid
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 3-chloro-4-hydroxy-N-(pyridin-4-ylmethyl)benzamide
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol