1,1'-Bis(di-tert-butylphosphino)ferrocene

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Names

[ CAS No. ]:
84680-95-5

[ Name ]:
1,1'-Bis(di-tert-butylphosphino)ferrocene

[Synonym ]:
MFCD01630818
1-[Bis(2-methyl-2-propanyl)phosphino]-1,2,3,4,5-cyclopentanepentayl - iron (2:1)
1,2,3,4,5-Cyclopentanepentayl, 1-[bis(1,1-dimethylethyl)phosphino]-, iron salt (2:1)
1,1'-Bis(di-tert-butylphosphino)ferrocene
1,1'-Bis[bis(2-methyl-2-propanyl)phosphino]ferrocene
Ferrocene, 1,1'-bis[bis(1,1-dimethylethyl)phosphino]-

Chemical & Physical Properties

[ Melting Point ]:
73-75ºC

[ Molecular Formula ]:
C26H44FeP2

[ Molecular Weight ]:
474.420

[ Exact Mass ]:
474.226776

[ PSA ]:
27.18000

[ LogP ]:
8.28090

[ Appearance of Characters ]:
crystal | orange to red

[ Water Solubility ]:
Insoluble in water.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1,1'-dilithioferrocene-(N,N,N',N'-tetramethylethylenediamine)-(1/2)
  • Di-tert-butylchlorophosphane

DownStream

Articles

Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline.

J. Org. Chem. 71 , 1969, (2006)

The inter- and intramolecular couplings of unactivated alkenes to 3,4-dihydroquinazolines with a Rh(I) catalyst are reported. Coupling between olefins and NH-3,4-dihydroquinazoline was found to occur ...

A convenient one-pot procedure to afford bicyclic molecules by stereospecific iron carbonyl mediated [6 + 2] ene-type cyclization: a possible approach to gelsemine.

J. Am. Chem. Soc. 125 , 13326, (2003)

A convenient one-pot procedure to prepare angularly substituted bicyclic and tricyclic molecules with excellent diastereoselectivity in good yield was developed, by Fe(CO)5 promoted cyclization. Three...

Sergeyev, S.; Hesse, M.

Synlett 8 , 1313, (2002)


More Articles

Related Compounds

  • (1,1'-bis(di-tert-butylphosphino)ferrocene)Ni(acac)
  • (1,1'-bis(di-tert-butylphosphino)ferrocene)Ni(η(2)-C2H4)
  • 1,1'-Bis(di-tert-butylphosphino)ferrocenepalladiumdichloride
  • Dibromo[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II)
  • [1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II) dichloride
  • Methanesulfonato 1,1'-Bis(di-tert-butylphosphino) ferrocene (2'-amino-1,1'-biphenyl-2-yl) palladium(II)