3-Hexyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene

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Names

[ Name ]:
3-Hexyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene

[Synonym ]:
2-(3-hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
MFCD11045447
2-(3-Hexyl-2-thienyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1,3,2-Dioxaborolane, 2-(3-hexyl-2-thienyl)-4,4,5,5-tetramethyl-

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
385.3±30.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₆H₂₇BO₂S

[ Molecular Weight ]:
294.260

[ Flash Point ]:
186.8±24.6 °C

[ Exact Mass ]:
294.182495

[ PSA ]:
46.70000

[ LogP ]:
4.17010

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.495

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Bromo-3-hexylthiophene
Isopropoxyboronic acid pinacol ester
N-(4-Chloro-2-cyanophenyl)-2,2,2-trifluoroacetamide
Pinacol
Triisopropylborate
Boron trichloride
3-hexylthiophene

DownStream

α,ω-Dihexylquaterthiophene,5,5μ-Bis(3-hexyl-2-thienyl)-2,2μ-bithiophene,DH-4T
2-bromo-3-hexyl-5-(3-hexylthiophen-2-yl)thiophene

Articles

Dithienothiophene (DTT)-based dyes for dye-sensitized solar cells: synthesis of 2,6-dibromo-DTT.

J. Org. Chem. 10th ed., 76 , 4088-4093, (2011)

A one-pot synthesis of 2,6-dibromodithieno[3,2-b;2',3'-d]thiophene (dibromo-DTT, 4) was developed. A key step was bromodecarboxylation of DTT-2,6-dicarboxylic acid, obtained by saponification of the d...

Hierarchical self-assembly of semiconductor functionalized peptide α-helices and optoelectronic properties.

J. Am. Chem. Soc. 22th ed., 133 , 8564-8573, (2011)

To determine the ability of semiconductors templated by α-helical polypeptides to form higher order structures and the charge carrier properties of the supramolecular assemblies, L-lysine was function...

p/n Switching of Ambipolar Bithiazole-Benzothiadiazole-Based Polymers in Photovoltaic Cells Balan, B.; et al.

Macromolecules 6th ed., 45 , 2709-2719, (2012)

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2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methoxybutanamido]cyclohexane-1-carboxylic acid
2-[(2R)-1-[6-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylhexanoyl]pyrrolidin-2-yl]acetic acid
rac-(3R,4S)-1-[(tert-butoxy)carbonyl]-4-(3-fluoro-4-methoxyphenyl)pyrrolidine-3-carboxylic acid
7-{[(9H-fluoren-9-yl)methoxy]carbonyl}-1-methyl-2-thia-7-azaspiro[4.4]nonane-9-carboxylic acid
2-{[(9H-fluoren-9-yl)methoxy]carbonyl}-7-methyl-2,7-diazaspiro[4.4]nonane-4-carboxylic acid
2-{[(9H-fluoren-9-yl)methoxy]carbonyl}-8,8-dimethyl-2-azaspiro[4.5]decane-4-carboxylic acid
rac-(3R,4S)-4-[4-(dimethylamino)phenyl]-1-{[(9H-fluoren-9-yl)methoxy]carbonyl}pyrrolidine-3-carboxylic acid
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