di-tert-butylsilyl bis(trifluoromethanesulfonate)

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Names

[ Name ]:
di-tert-butylsilyl bis(trifluoromethanesulfonate)

[Synonym ]:
di-tert-butylsilanediyl bis(trifluoromethanesulfonate)
Di(tert-butyl)([(trifluoromethyl)sulfonyl]oxy)silyl trifluoromethanesulfonate
[ditert-butyl(trifluoromethylsulfonyloxy)silyl] trifluoromethanesulfonate
Bis(2-methyl-2-propanyl)silanediyl bis(trifluoromethanesulfonate)
MFCD00010581
Methanesulfonic acid, 1,1,1-trifluoro-, bis(1,1-dimethylethyl)silylene ester

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
275.6±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₁₈F₆O₆S₂Si

[ Molecular Weight ]:
440.452

[ Flash Point ]:
90.6±0.0 °C

[ Exact Mass ]:
440.021820

[ PSA ]:
103.50000

[ LogP ]:
6.36

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.413

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Trifluoromethanesulfonic acid
Di-tert-butylchlorosilane
Di-tert-butyl(dichloro)silane

DownStream

Articles

Synthesis of a versatile (S)-3-(hydroxymethyl)butane-1,2,4-triol building block and its application for the stereoselective synthesis of N-homoceramides.

Org. Lett. 7 , 5769, (2005)

[structures: see text] A versatile (S)-3-(hydroxymethyl)butane-1,2,4-triol building block has been synthesized starting from D-isoascorbic acid, a common food preservative. The key transformation in t...

Z. Anorg. Allg. Chem. 618 , 144, (1992)

Chem. Ber. 125 , 47, (1992)

(Di-tert-butylsilyl)bis(trimethylsilyl)methan
Brom(di-tert-butylsilyl)bis(trimethylsilyl)methan
(4aR,6S,7R,8R,8aR)-2,2-di-tert-Butyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3,2]dioxasiline-7,8-diol
5-amino-3-(2,2-di-tert-butyl-7-hydroxy-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-3H-thiazolo[4,5-d]pyrimidin-2-one
(4aR,6S,7R,8R,8aS)-7,8-bis(benzyloxy)-2,2-di-tert-butyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3,2]dioxasiline
Di-tert-butyl(bis(dimethylamino)methyl)phosphine
4-Methyl-3-[(pyrrolidin-3-yl)methyl]pyridine
5-(4-Methylpyridin-3-yl)-1,3-oxazolidin-2-one
ethyl 5-[(3-methoxyphenoxy)methyl]-1-methyl-1H-pyrazole-4-carboxylate
ethyl 5-[(4-chlorophenoxy)methyl]-1-methyl-1H-pyrazole-4-carboxylate
Ethyl 1-methyl-5-(pyridin-2-yloxymethyl)pyrazole-4-carboxylate
Ethyl 1-ethyl-5-formyl-1H-pyrazole-4-carboxylate
4-Amino-3-(4-methylpyridin-3-yl)butanoic acid
(E)-(2-(1-(Ethoxycarbonyl)cyclopropyl)vinyl)boronic acid pinacol ester
2-(3-Methyl-1-benzofuran-5-yl)acetonitrile
2-(1-acetylpiperidin-4-yl)-1H-imidazole-4-carboxylic acid

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