Lithium methoxide

Suppliers

Names

[ CAS No. ]:
865-34-9

[ Name ]:
Lithium methoxide

[Synonym ]:
lithium hydroxide monohydrate
LITHIUMMETHOXID
Lithiummethoxide
Methoxylithium
EINECS 212-737-7
Lithium methylate
MFCD00036357
methanol,lithiumsalt
Lithium methoxide
Lithiummethoxide,min.
Lithium methanolate
Methanol, lithium salt (1:1)
lithium methoxide solution

Chemical & Physical Properties

[ Density]:
0.85 g/mL at 20 °C

[ Boiling Point ]:
64.6 °C

[ Melting Point ]:
500°C

[ Molecular Formula ]:
CH3LiO

[ Molecular Weight ]:
37.975

[ Flash Point ]:
52 °F

[ Exact Mass ]:
38.034393

[ PSA ]:
23.06000

[ LogP ]:
0.04670

[ Storage condition ]:
Flammables area

[ Stability ]:
Stable, but reacts violently with water. Highly flammable. Store under dry inert gas.

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H251-H301-H311-H314-H331-H370

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P235 + P410-P260-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F: Flammable;T: Toxic;C: Corrosive;

[ Risk Phrases ]:
R14;R17;R34

[ Safety Phrases ]:
S8-S16-S26-S43-S45-S36/37/39

[ RIDADR ]:
UN 3274 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
4.2

Synthetic Route

Precursor & DownStream

Precursor

  • Methanol
  • 1,2-dimethoxyethane
  • n-Butyllithium
  • dimethyl ether
  • Diethyl ether
  • 1-Iodo-2-methoxyethane
  • Phenyllithium

DownStream

  • 6',6''-BIS(2-PYRIDYL)-2,2':4',4'':2'',2'''-QUATERPYRIDINE
  • 3-Pyridylboronic acid
  • 4'-methoxy-2,2':6',2''-terpyridine
  • 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-2,6-dipyridin-2-ylpyridine
  • Dibenzyl ether
  • 3-Methoxy-5-nitrobenzoic acid
  • ETHYL 3-METHOXY-5-NITROBENZOATE
  • Methyl 1-Naphthaleneacetate
  • 1-Butene
  • 1-Methoxybutane

Articles

Ali, A.F. et al.

J. Mater. Res. 14 , 1510, (1999)


More Articles


Related Compounds

  • LITHIUM NIOBIUM METHOXIDE
  • lithium citrate
  • lithium,trimethyl(prop-2-enyl)silane
  • lithium n-butylcyclopentadienide
  • lithium pyruvate
  • lithium α-carbanion of propionitrile