Triethyl phosphonoacetate

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Names

[ CAS No. ]:
867-13-0

[ Name ]:
Triethyl phosphonoacetate

[Synonym ]:
EINECS 212-757-6
Triethyl phosphonacetate
Triethyl phosphonoac
Triethyl phosphono acetate
(ETHOXYCARBONYLMETHYL)DIETHOXYPHOSPHINEOXIDE
AURORA KA-1452
diethyl ethoxycarbonylmethanephosphonate
Ethyl (diethoxyphosphoryl)acetate
ethyl diethoxyphosphorylacetate
MFCD00009177
PHOSPHONOACETIC ACID ETHYL ESTER
(ETHOXYCARBONYLMETHYL)-DIETHOXYPHOSPHINE OXIDE
TRIETHYL PHOSPHONACETIC ACID
diethoxyphosphoryl-acetic acid ethyl ester
TRIETHYLPHOSPHONEACETATE
TRIETHYLPHOSPHONOAETATE
Triethylphosphonoacetate
TRENBOLONE HEXAHYDROBENZYL CARBONATE
Acetic acid, 2-(diethoxyphosphinyl)-, ethyl ester
TRIETHYL PHOSPHONOACEATE
ethyl 2-(diethoxyphosphoryl)acetate
tl465
Triethyl Phosphonoacetate ( Tepp)
TRIETHYL PHOSPHONOACETATE FOR SYNTHESIS
Triethyl phosphonoacetate
TRIETHYLPHOSPONOACETATE
Diethylphosphonoacetic Acid Ethyl Ester
Trietyl Phosphonoacetate
phosphonoacetic acid triethyl ester
Diethyl [(ethoxycarbonyl)methyl]phosphonate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
287.4±23.0 °C at 760 mmHg

[ Melting Point ]:
-24°C

[ Molecular Formula ]:
C8H17O5P

[ Molecular Weight ]:
224.19

[ Flash Point ]:
141.6±42.9 °C

[ Exact Mass ]:
224.081360

[ PSA ]:
71.64000

[ LogP ]:
0.92

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.424

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AG9800000
CHEMICAL NAME :
Acetic acid, diethylphosphono-, ethyl ester
CAS REGISTRY NUMBER :
867-13-0
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C8-H17-O5-P
MOLECULAR WEIGHT :
224.22
WISWESSER LINE NOTATION :
OPO&O&2&2&1VO2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,15,1953
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1180 mg/m3/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,NOV1942

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38;R51/53

[ Safety Phrases ]:
S61-S37/39-S26

[ RIDADR ]:
UN 3082 9/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
AG9800000

[ Hazard Class ]:
9.0

[ HS Code ]:
2931901990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ethyl 2-bromoacetate
  • Triethyl phosphite
  • ethyl chloroacetate
  • Diethyl phosphite
  • Triethyl phosphate
  • Diethyl methylphosphonate
  • diethyl sodium phosphite
  • 2-(5-methyl-2-phenyl-4-oxazolyl)methyl-5-benzofurancarboxaldehyde
  • Methyl 2-(diethoxyphosphoryl)acetate

DownStream

  • ethyl 3-(4-tert-butylphenyl)prop-2-enoate
  • Ethyl 3-(4-(trifluoromethyl)phenyl)acrylate
  • 4-(Trifluoromethyl)benzoic acid
  • ethyl 2-diethoxyphosphoryl-3-trimethylsilylpropanoate
  • 3-(3-PHENOXY-PHENYL)-PROPAN-1-OL
  • ethyl 1-diethoxyphosphorylcyclopropane-1-carboxylate
  • ethyl 2-diethoxyphosphorylpent-4-enoate
  • ethyl 2-diethoxyphosphoryl-2-(prop-2-enyl)pent-4-enoate
  • ethyl 6-chlorohex-2-enoate
  • ethyl 4,4-diethoxybut-2-enoate

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

"Carba" peptide bond surrogates. Different approaches to Gly-psi(CH2-CH2)-D,L-Xaa pseudo-dipeptide units.

Int. J. Pept. Protein Res. 39(3) , 273-7, (1992)

Racemic "carba" pseudo-dipeptide units such as Gly-psi(CH2-CH2)-D,L-Xaa were obtained either through the Horner-Emmons condensation of N-tert.-butyloxycarbonyl-beta alaninal with the appropriate subst...

J. Boutagy, R. Thomas

Chem. Rev. 74 , 87, (1974)

T. Minami, J. Motoyoshiya

Synthesis , 333, (1991)


More Articles

Related Compounds

  • TRIETHYL PHOSPHONOACETATE
  • Triethyl Phosphonoacetate
  • triethyl phosphonoacetate
  • triethyl phosphonoacetate
  • Triethyl Phosphonoacetate-13C2
  • Triethyl phosphonoacetate-1-13C
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 4-Cyclopropyl-3-nitrobenzoic acid methyl ester
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide