Tricyanoaminopropene

Suppliers

Names

[ CAS No. ]:
868-54-2

[ Name ]:
Tricyanoaminopropene

[Synonym ]:
Tricyanoaminopropene
EINECS 212-777-5
1-Propene-1,1,3-tricarbonitrile, 2-amino-
MFCD00001851
2-Amino-1-propene-1,1,3-tricarbonitrile
1,1,3-tricyano-2-amino-1-propene
2-aminoprop-1-ene-1,1,3-tricarbonitrile

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
591.9±50.0 °C at 760 mmHg

[ Melting Point ]:
171-173 °C(lit.)

[ Molecular Formula ]:
C6H4N4

[ Molecular Weight ]:
132.123

[ Flash Point ]:
311.8±30.1 °C

[ Exact Mass ]:
132.043594

[ PSA ]:
97.39000

[ LogP ]:
-0.13

[ Vapour Pressure ]:
0.0±1.7 mmHg at 25°C

[ Index of Refraction ]:
1.541

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UD2340000
CHEMICAL NAME :
1-Propene-1,1,3-tricarbonitrile, 2-amino-
CAS REGISTRY NUMBER :
868-54-2
BEILSTEIN REFERENCE NO. :
1756131
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C6-H4-N4
MOLECULAR WEIGHT :
132.14
WISWESSER LINE NOTATION :
NCYCN&UYZ&1CN

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01433

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
UN 3259 8/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
UD2340000

[ HS Code ]:
2926909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Malononitrile
  • benzene
  • thf
  • Diethyl ether
  • Hydrochloric acid
  • Ethanol
  • nitrogen dioxide

DownStream

  • 5-Amino-4-cyano-3-(cyanomethyl)pyrazole
  • 4,6-Diamino-2-bromonicotinonitrile
  • 1H-Pyrazole-3-aceticacid, 5-amino-4-(aminocarbonyl)-
  • 5-amino-4-cyano-3-cyanomethyl-1-phenylpyrazole
  • 2,4-diamino-6-sulfanylidene-1H-pyridine-3-carbonitrile
  • 4,6-diamino-1-(4-chlorophenyl)-2-oxo-3H-pyrrolo[2,3-b]pyridine-5-carbonitrile
  • 4,6-DIAMINO-1-(4-METHOXY-PHENYL)-2-OXO-2,3-DIHYDRO-1H-PYRROLO[2,3-B]PYRIDINE-5-CARBONITRILE
  • 4,6-diamino-2-oxo-1-phenyl-3H-pyrrolo[2,3-b]pyridine-5-carbonitrile
  • 1H-Pyrazolo[4,3-c]pyridine-7-carboxylicacid,3-amino-4-hydroxy-(6CI)
  • 2-(3-cyano-4,6-dimethyl-1H-pyridin-2-ylidene)propanedinitrile

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis, characterization and optical properties of merocyanines derived from malononitrile dimer. Alias S, et al.

Tetrahedron Lett. 48(37) , 6539-6542, (2007)

An improved and facile synthesis of 2-amino-1, 1, 3-tricyanopropene. Mittelbach M.

Monatsh. Chem 116(5) , 689-691, (1985)


More Articles