Di-tert-Butyl azodicarboxylate

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Names

[ CAS No. ]:
870-50-8

[ Name ]:
Di-tert-Butyl azodicarboxylate

[Synonym ]:
di-tert-butylazodicarboxylate
EINECS 212-796-9
MFCD00015001
Bis(2-methyl-2-propanyl) 1,2-diazenedicarboxylate
Boc-N=N-Boc
Di-tert-Butyl azodic
tert-butyl azodicarboxylate
di-tert-butylazadicarboxylate
Di-tert-butyl azodicarboxylate
DI-TERT-BUTYL AZODICARBOXYALTE
DI-T-BUTYL AZODICARBOXYLATE
tBuO2CN=NCO2tBu
1,2-Diazenedicarboxylic acid, bis(1,1-dimethylethyl) ester
Di-tert-butyl diazene-1,2-dicarboxylate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
287.1±9.0 °C at 760 mmHg

[ Melting Point ]:
89-92 °C(lit.)

[ Molecular Formula ]:
C10H18N2O4

[ Molecular Weight ]:
230.261

[ Flash Point ]:
107.2±13.2 °C

[ Exact Mass ]:
230.126663

[ PSA ]:
77.32000

[ LogP ]:
3.24

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.460

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
Insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H360FD

[ Precautionary Statements ]:
P201-P308 + P313

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39-S16

[ RIDADR ]:
1325

[ WGK Germany ]:
3

[ RTECS ]:
VZ2275000

[ HS Code ]:
2927000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Di-Tert-Butyl Hydrazo dicarboxylate
  • Di-tert-butyl dicarbonate
  • bis(acetato-O)triphenylbismuth(V)

DownStream

  • 1-(Pyridin-2-yl)piperazin-2-one
  • Di-Tert-Butyl Hydrazo dicarboxylate
  • Boc3-Hydrazine
  • 1,2-Pyridazinedicarboxylicacid, 3,6-dihydro-, 1,2-bis(1,1-dimethylethyl) ester
  • 2,3-Diazabicyclo[2.2.1]heptane-2,3-dicarboxylicacid, 2,3-bis(1,1-dimethylethyl) ester
  • tert-butyl N-[(2-methylpropan-2-yl)oxycarbonylamino]-N-phenylcarbamate
  • Tetrathiobernsteinsaeure-dimethylester

Customs

[ HS Code ]: 2927000090

[ Summary ]:
2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Axially chiral guanidine as highly active and enantioselective catalyst for electrophilic amination of unsymmetrically substituted 1,3-dicarbonyl compounds.

J. Am. Chem. Soc. 128 , 16044, (2006)

A newly designed axially chiral guanidine is found to function as an effective platform for asymmetric induction at the alpha-carbon of unsymmetrically substituted 1,3-dicarbonyl compounds. Highly eff...

Chirally aminated 2-naphthols--organocatalytic synthesis of non-biaryl atropisomers by asymmetric Friedel-Crafts amination.

Angew. Chem. Int. Ed. Engl. 45(7) , 1147-1151, (2006)

Catalytic Enantioselective Reaction of α-Aminoacetonitriles Using Chiral Bis(imidazoline) Palladium Catalysts.

Angew. Chem. Int. Ed. Engl. 54(28) , 8198-202, (2015)

The catalytic enantioselective reaction of diphenylmethylidene-protected α-aminoacetonitriles with imines has been developed. Good yields and diastereo- and enantioselectivities were observed for the ...


More Articles

Related Compounds

  • di-tert-butyl azodicarboxylate
  • Di-tert-butyl azodicarboxylate
  • Di-tert-butyl azodicarboxylate
  • Di-tert-butyl (4-amino-6-Methylpyrimidin-2-yl)carbamate
  • Di-tert-butyl butane-1,4-diylbis((3-aminopropyl)carbamate)
  • di-tert-Butyl (2S,3R)-3-(hydroxymethyl)azetidine-1 ,2-dicarboxylate...
  • 2-[(6,7-dimethoxy-3,4-dihydroisoquinolin-2(1H)-yl)methyl]-6-(thiophen-2-yl)pyridazin-3(2H)-one
  • N-[3-(propan-2-yl)-1H-1,2,4-triazol-5-yl]-2-[1-(1H-tetrazol-1-ylmethyl)cyclohexyl]acetamide
  • [4-(3-methoxyphenyl)piperazino][1-methyl-3-(2-thienyl)-1H-pyrazol-5-yl]methanone
  • 4-(3,4-dichlorophenyl)-N-{2-[(2-hydroxyphenyl)amino]-2-oxoethyl}piperazine-1-carboxamide
  • N-(1H-indol-4-yl)-3-(1-oxo-1,3-dihydro-2H-isoindol-2-yl)propanamide
  • 1-(6-chloropyridazin-3-yl)-N-(4-hydroxyphenyl)piperidine-3-carboxamide
  • N-(2,3-dihydro-1,4-benzodioxin-6-yl)-4-([1,2,4]triazolo[4,3-a]pyridin-3-yl)butanamide
  • 7-[2-(1-cyclohexenyl)ethyl]-5-methylpyrido[3,4-e][1,2,4]triazolo[1,5-a]pyrimidin-6(7H)-one
  • 2-[4-(2,2-dichlorocyclopropyl)phenoxy]-2-methyl-N-(1-methyl-1H-pyrazol-4-yl)propanamide
  • 2-(2-methoxyethyl)-4-[(2-phenylmorpholino)carbonyl]-1(2H)-isoquinolinone
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