Sodium formaldehyde bisulfite

Suppliers

Names

[ CAS No. ]:
870-72-4

[ Name ]:
Sodium formaldehyde bisulfite

[Synonym ]:
Formaldehyde-sodium bisulfite adduct
MFCD00044664
Sodium formaldehyde bisulfite
Methanesulfonic acid, 1-hydroxy-, sodium salt (1:1)
Sodium hydroxymethanesulfonate
EINECS 212-800-9
Hydroxymethanesulfonate, sodium salt
PS
PN
Hydroxymethanesulfonic acid monosodium salt
Sodium hydroxymethanesulphonate

Chemical & Physical Properties

[ Boiling Point ]:
184ºC

[ Melting Point ]:
200 °C (dec.)(lit.)

[ Molecular Formula ]:
CH3NaO4S

[ Molecular Weight ]:
134.087

[ Flash Point ]:
184 °C

[ Exact Mass ]:
133.964981

[ PSA ]:
85.81000

[ Storage condition ]:
-20°C

[ Water Solubility ]:
800 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
PB2200000
CHEMICAL NAME :
Methanesulfonic acid, hydroxy-, sodium salt
CAS REGISTRY NUMBER :
870-72-4
LAST UPDATED :
199710
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C-H3-O4-S.Na
MOLECULAR WEIGHT :
134.09
WISWESSER LINE NOTATION :
WSQ1Q &-NA-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1541 No. of Facilities: 3759 (estimated) No. of Industries: 35 No. of Occupations: 19 No. of Employees: 13847 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1541 No. of Facilities: 12458 (estimated) No. of Industries: 56 No. of Occupations: 45 No. of Employees: 67397 (estimated) No. of Female Employees: 13233 (estimated)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1

[ RTECS ]:
PB2200000

[ HS Code ]:
2942000000

Synthetic Route

Precursor & DownStream

Precursor

  • Formaldehyde
  • Methanesulfonic acid,1-(phenylamino)-, sodium salt (1:1)
  • p-methylanilinomethanesulfonate
  • p-chloroanilinomethanesulfonate
  • anilinomethanesulfonate
  • m-chloroanilinomethanesulfonate

DownStream

  • α-Aminoisobutyronitrile
  • [(4-methylphenyl)amino]methanesulfonic acid
  • Methanesulfonic acid,1-(phenylamino)-, sodium salt (1:1)
  • Methanesulfonic acid,1,1',1'',1'''-(1,2-ethanediyldinitrilo)tetrakis-, sodium salt (1:4)
  • Methanesulfonic acid,1-(phenylamino)-
  • Acetonitrile,2-[(4-methylphenyl)amino]-
  • Mesulfamide
  • Methanesulfonic acid,1-[(3-chlorophenyl)amino]-, sodium salt (1:1)
  • formate
  • 3-[6-(1,3-thiazolidin-3-yl)hexyl]-1,3-thiazolidine

Customs

[ HS Code ]: 2942000000

Articles

Improved production of 3-hydroxypropionaldehyde by complex formation with bisulfite during biotransformation of glycerol.

Biotechnol. Bioeng. 110(4) , 1243-8, (2013)

3-Hydroxypropionaldehyde (3HPA) is an important specialty chemical which can be produced from glycerol using resting cells of Lactobacillus reuteri. This biocatalytic route, however, suffers from subs...

Determination of free and reversibly-bound sulfite in selected foods by high-performance liquid chromatography with fluorometric detection.

J. AOAC Int. 91(1) , 98-102, (2008)

A rapid and accurate method for measuring low part-per-million levels of free and reversibly-bound sulfites in selected foods by using high-performance liquid chromatography (HPLC) with fluorometric d...

Light-induced formation of hydroxyl radicals in fog waters determined by an authentic fog constituent, hydroxymethanesulfonate.

Chemosphere 51(3) , 175-9, (2003)

The determination of the photo-production rate of hydroxyl radical (OH) in atmospheric liquids is of fundamental importance to an understanding of atmospheric aquatic chemistry. Recently, several stud...


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Related Compounds

  • sodium,formaldehyde,hydrogen sulfite,2-methylphenol
  • sodium,formaldehyde,hydrogen sulfite,1,3,5-triazine-2,4,6-triamine
  • sodium,formaldehyde,4-methylbenzenesulfonate,phenol
  • sodium,formaldehyde,2-hydroxybenzenesulfonate,4-(4-hydroxyphenyl)sulfonylphenol
  • sodium,formaldehyde,naphthalene-1-sulfonate
  • sodium,formaldehyde,3-hydroxyphenolate