5-Chloro-1-methylimidazole

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Names

[ CAS No. ]:
872-49-1

[ Name ]:
5-Chloro-1-methylimidazole

[Synonym ]:
5-Chloro-1-methylimidazole
MFCD00014505
EINECS 212-827-6

Chemical & Physical Properties

[ Density]:
1.25 g/mL at 25 °C(lit.)

[ Boiling Point ]:
82-85 °C11 mm Hg(lit.)

[ Melting Point ]:
82-85°C(11 mmHg)

[ Molecular Formula ]:
C4H5ClN2

[ Molecular Weight ]:
116.54900

[ Flash Point ]:
205 °F

[ Exact Mass ]:
116.01400

[ PSA ]:
17.82000

[ LogP ]:
1.07350

[ Index of Refraction ]:
n20/D 1.511(lit.)

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • NN'-Dimethyloxamide
  • N-formylglycine methylamide
  • N',N'-dimethyloxamide
  • 1-allyl-4-chloro-3-methyl-imidazolium, bromide

DownStream

  • 5-Chloro-1-methyl-4-nitroimidazole
  • methylimidazole
  • (5-Chloro-1-methyl-1H-imidazol-2-yl)methanol
  • 5-chloro-1-methylimidazole-4-sulfonic acid
  • 5-[(TRIMETHYLSILYL)]-1-METHYLIMIDAZOLE
  • 1-[(3-bromo-4-methoxyphenyl)methyl]-4-[(2,3,4-trimethoxyphenyl)methyl]piperazine
  • (5-chloro-1-methylimidazol-2-yl)-(furan-2-yl)methanone

Customs

[ HS Code ]: 2933290090

[ Summary ]:
2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

First success of catalytic epoxidation of olefins by an electron-rich iron(III) porphyrin complex and H2O2: imidazole effect on the activation of H2O2 by iron porphyrin complexes in aprotic solvent.

J. Inorg. Biochem. 80(3-4) , 219-25, (2000)

An electron-rich iron(III) porphyrin complex (meso-tetramesitylporphinato)iron(III) chloride [Fe(TMP)Cl], was found to catalyze the epoxidation of olefins by aqueous 30% H2O2 when the reaction was car...

An efficient route to 5-iodo-1-methylimidazole: synthesis of xestomanzamine A. Panosyan FB and Still IWJ.

Can. J. Chem. 79(7) , 1110-14, (2001)


More Articles

Related Compounds

  • 5-Chloro-1-methylimidazole nitrate
  • 5-chloro-1-methylimidazole-2-carbaldehyde
  • 5-chloro-1-methylimidazole-4-sulfonic acid
  • 5-chloro-1-methylimidazole-4-sulfonyl chloride
  • 5-Chloro-1-ethyl-2-methylimidazole
  • 5-chloro-N-[2-(4-hydroxyphenyl)ethyl]-1-methylimidazole-4-sulfonamide