3-methoxybenzyl bromide

Suppliers

Names

[ CAS No. ]:
874-98-6

[ Name ]:
3-methoxybenzyl bromide

[Synonym ]:
BENZENE,1-(BROMOMETHYL)-3-METHOXY-
MFCD00216590
Benzene, 1-(bromomethyl)-3-methoxy-
3-METHOXY BENZYL BROMIDE
3-METHOXYBENZYLBROMIDE
3-Methoxybenzyl Bromide
3-(Bromomethyl)phenyl methyl ether
1-(Bromomethyl)-3-methoxybenzene

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
241.1±15.0 °C at 760 mmHg

[ Molecular Formula ]:
C8H9BrO

[ Molecular Weight ]:
201.061

[ Flash Point ]:
95.4±21.5 °C

[ Exact Mass ]:
199.983673

[ PSA ]:
9.23000

[ LogP ]:
2.83

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.551

[ Storage condition ]:
-20?C Freezer

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Hazard Class ]:
8.0

[ HS Code ]:
2909309090

Synthetic Route

Precursor & DownStream

Precursor

  • 3-Methoxybenzyl alcohol
  • 3-Methylanisole
  • 3-methoxy-1-[(ethoxymethoxy)methyl]benzene
  • 3-methoxy-1-(methoxymethoxy)methyl benzene
  • 1-(dimethoxymethyl)-3-methoxybenzene
  • 3-Methoxybenzoic acid
  • m-Anisaldehyde
  • 3-Hydroxybenzyl alcohol
  • 1,3-Dibromo-5,5-dimethylhydantoin

DownStream

  • Diethyl (3-methoxybenzyl)phosphonate
  • CYCLOPROPYL 2-(3-METHOXYPHENYL)ETHYL KETONE
  • 3-Methoxy-2-phenylethylamine
  • Benzoic acid,2-[[(3-methoxyphenyl)methyl][(4-methylphenyl)sulfonyl]amino]-
  • 1-methoxy-3-phenylmethoxy-benzene
  • 2-[(3-methoxyphenyl)methyl]piperazine
  • m-Cresol
  • 3-Methylanisole
  • m-Anisaldehyde
  • 4-(3-METHOXYPHENYL)-1-BUTENE

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

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Arch. Pharm. (Weinheim) 348(1) , 55-61, (2015)

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J. Org. Chem. 76(7) , 2355-9, (2011)

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Mild conversion of beta-diketones and beta-ketoesters to carboxylic acids.

J. Org. Chem. 71 , 4516-4520, (2006)

A mild protocol for the conversion of beta-ketoesters and beta-diketones to carboxylic acids with use of CAN in CH3CN is described. The method is compatible with a number of functional groups, and can...


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Related Compounds

  • 4-Cyano-3-methoxybenzyl Bromide
  • 2-bromo-3-methoxybenzyl bromide
  • 5-bromo-3-methoxybenzyl bromide
  • 2-bromo-3-methoxybenzyl bromide
  • 4-chloro-3-methoxybenzyl bromide
  • 4-Methyl-3-methoxybenzyl bromide
  • trans-4-(4-Methyl-1-piperazinyl)-3-pyrrolidinol trihydrochloride
  • (3S,4S)-4-(morpholin-4-yl)pyrrolidin-3-ol hydrochloride
  • (3S)-3-acetamido-3-(pyridin-2-yl)propanoic acid
  • 1-[(4-Bromophenyl)methyl]-1H-tetrazol-5-amine
  • Ecgonine methylester-D3 HCl; Methylecgonine-D3 hydrochloride; Methyl (1R,2R,3S,5S)-3-hydroxy-8-trideuteromethyl-8-azabicyclo[3.2.1]octane-2-carboxylate hydrochloride
  • 6-Acetyl-3-amino-pyrazine-2-carboxylic acid methyl ester
  • 1-(2-Methoxy-4-methylphenyl)cyclopentane-1-carboxylic acid
  • 3-Amino-6-(tetrahydrofuran-2-yl)pyrazine-2-carboxylic acid methyl ester
  • rac a-Ethyl DOPA Hydrobromide
  • 4-Ethyl-5-fluoropyrimidine Hydrochloride
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