3-methoxybenzyl bromide
Suppliers
Names
[ CAS No. ]:
874-98-6
[ Name ]:
3-methoxybenzyl bromide
[Synonym ]:
BENZENE,1-(BROMOMETHYL)-3-METHOXY-
MFCD00216590
Benzene, 1-(bromomethyl)-3-methoxy-
3-METHOXY BENZYL BROMIDE
3-METHOXYBENZYLBROMIDE
3-Methoxybenzyl Bromide
3-(Bromomethyl)phenyl methyl ether
1-(Bromomethyl)-3-methoxybenzene
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
241.1±15.0 °C at 760 mmHg
[ Molecular Formula ]:
C8H9BrO
[ Molecular Weight ]:
201.061
[ Flash Point ]:
95.4±21.5 °C
[ Exact Mass ]:
199.983673
[ PSA ]:
9.23000
[ LogP ]:
2.83
[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.551
[ Storage condition ]:
-20?C Freezer
MSDS
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C: Corrosive;
[ Risk Phrases ]:
R34
[ Safety Phrases ]:
S26-S27-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Hazard Class ]:
8.0
[ HS Code ]:
2909309090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2909309090
[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Arch. Pharm. (Weinheim) 348(1) , 55-61, (2015)
The current structure-activity relationship of profens (i.e., 2-arylpropionic acid derivatives, a class of non-steroidal anti-inflammatory drugs) discusses the importance of α-monomethyl substitution ...
J. Org. Chem. 76(7) , 2355-9, (2011)
An experimentally simple sequential one-pot RuAAC reaction, affording 1,5-disubstituted 1H-1,2,3-triazoles in good to excellent yields starting from an alkyl halide, sodium azide, and an alkyne, is re...
J. Org. Chem. 71 , 4516-4520, (2006)
A mild protocol for the conversion of beta-ketoesters and beta-diketones to carboxylic acids with use of CAN in CH3CN is described. The method is compatible with a number of functional groups, and can...