Dess-Martin periodinane

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Names

[ CAS No. ]:
87413-09-0

[ Name ]:
Dess-Martin periodinane

[Synonym ]:
1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro-
MFCD00130127
EINECS 200-009-0
1,1,1-tris(acetyloxy)-1λ,2-benziodoxol-3(1H)-one
(1,1-diacetyloxy-3-oxo-1λ<sup>5</sup>,2-benziodoxol-1-yl) acetate
1,1,1-Triacetoxy-1λ,2-benziodoxol-3(1H)-one

Chemical & Physical Properties

[ Density]:
1.369 g/mL at 25 °C

[ Boiling Point ]:
40 °C

[ Melting Point ]:
130-133 °C(lit.)

[ Molecular Formula ]:
C13H13IO8

[ Molecular Weight ]:
424.142

[ Flash Point ]:
>221 °F

[ Exact Mass ]:
423.965515

[ PSA ]:
105.20000

[ LogP ]:
1.95370

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R40;R8

[ Safety Phrases ]:
S26-S36-S36/37-S24/25-S23-S17-S45-S36/37/39

[ RIDADR ]:
UN 1593 6.1/PG 3

[ WGK Germany ]:
3

[ Hazard Class ]:
6.1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Ethanoic anhydride
  • 2-iodoxybenzoic acid
  • acetic acid
  • 2-Iodobenzoic acid

DownStream

  • 5,8-Dimethoxy-2-tetralone
  • 4-Iodoaniline
  • 1-Acetoxy-1,2-benziodoxol-3-(1H)-one
  • 3,4,5-Trimethoxybenzaldehyde
  • acetic acid
  • Cyclooctanone
  • 3-indazol-1-ylpropanoic acid
  • 2-Iodobenzoic acid
  • tetrahydro-2-furyl acetate
  • 1-[[(4-METHYLPHENYL)SULPHONYL]OXY]-1,2-BENZIODOXOL-3(1H)-ONE

Related Compounds

  • DESS-MARTINPERIODINANE
  • 2-iodoxybenzoic acid
  • hydroxyl-2-pyridone
  • 1-(Cyclopropylmethyl)cyclopentane-1-carboxylic acid
  • 5-Chloro-6-methoxypicolinonitrile
  • 2-Chloro-5-[4-(4-chlorophenyl)-2,3-dihydro-3-methyl-1,1-dioxido-1,2,5-thiadiazol-3-yl]pyridine
  • ethyl 1-(4-(aminosulfonyl)phenyl)-3-(trifluoromethyl)-5-p-tolyl-1H-pyrazole-4-carboxylate
  • 2-(2,5-Dimethoxyphenylthio)-6-methoxybenzaldehyde
  • 5-Methyl-2-(methylthio)oxazolo[5,4-b]pyridine
  • 3-(6-Fluoro-1-oxoisoindolin-2-yl)propanoic acid
  • 4-(Aminocarbonyl)-3-[(1-cyclopropylethyl)amino]benzoic acid
  • 3-(Acetylamino)-4-(aminocarbonyl)benzoic acid
  • 4-(Aminocarbonyl)-3-(benzylamino)benzoic acid
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