4-Bromo-2-nitroaniline

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Names

[ CAS No. ]:
875-51-4

[ Name ]:
4-Bromo-2-nitroaniline

[Synonym ]:
p-bromonitroaniline
2-Nitro-4-bromoaniline
4-Bromo-2-nitro-phenylamine
1-amino-4-bromo-2-nitrobenzene
Aniline,4-bromo-2-nitro
p-Bromo-o-nitroaniline
ZR DE BNW
4-Bromo-2-nitroaniline
4-Bromo-2-nitrobenzeneamine
Benzenamine,4-bromo-2-nitro
4-Bromo-2-nitrobenzenamine
4-bromo-o-nitroaniline
4-bromo-2-nitro-aniline
4-bromo-2-nitrooaniline
MFCD00041312
Benzenamine, 4-bromo-2-nitro-

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
308.7±22.0 °C at 760 mmHg

[ Melting Point ]:
110-113 °C(lit.)

[ Molecular Formula ]:
C6H5BrN2O2

[ Molecular Weight ]:
217.020

[ Flash Point ]:
140.5±22.3 °C

[ Exact Mass ]:
215.953430

[ PSA ]:
71.84000

[ LogP ]:
2.75

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.670

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BW9370000
CHEMICAL NAME :
Aniline, 4-bromo-2-nitro-
CAS REGISTRY NUMBER :
875-51-4
BEILSTEIN REFERENCE NO. :
2210198
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C6-H5-Br-N2-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,12,1953

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H317-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
BW9370000

[ HS Code ]:
2921420090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Nitroaniline
  • N-(4-Bromo-2-nitrophenyl)acetamide
  • Dichloromethane
  • N-methylmorpholine-N-oxide
  • 5-Benzimidazolecarboxylic Acid
  • 4-Bromoaniline
  • 2,4,4,6-tetrabromo-2,5-cyclohexadienone
  • 4-Bromoacetanilide
  • 1,4-Dibromo-2-nitrobenzene
  • 4-(2-nitrophenylazo)-anisole

DownStream

  • 4-Bromo-2-chloro-6-nitroaniline
  • 5-Bromo-1H-benzotriazole
  • 6-Bromo-8-quinolinamine
  • 7-Bromo-1,2,4-benzotriazin-3-amine
  • 5-Bromobenzo[c][1,2,5]oxadiazole
  • 5-Bromo-1H-benzo[d]imidazole
  • Benzo[c][1,2,5]oxadiazol-5-ylboronic acid
  • QUINOXALINE, 6-BROMO-2,3-DIMETHYL-
  • 2-Nitroaniline
  • o-Phenylenediamine

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Related Compounds

  • N-methyl-4-bromo-2-nitroaniline
  • N-t-Butyl 4-bromo-2-nitroaniline
  • 5-benzyloxy-4-bromo-2-nitroaniline
  • N,N-Dimethyl-4-bromo-2-nitroaniline
  • n-cyclopropyl 4-bromo-2-nitroaniline
  • 4-Bromo-2-chloro-3-nitroaniline
  • 1-Acryloyl-N-(4-ethylphenyl)piperidine-4-carboxamide
  • N-(2-Methylbutan-2-yl)-1-prop-2-enoylpiperidine-4-carboxamide
  • N-(2,6-dimethylphenyl)-2-{[1-(prop-2-enoyl)piperidin-4-yl]formamido}acetamide
  • 1,1-Bis[(4-fluorophenyl)thio]-1,2,3,4-tetrahydro-6-iodonaphthalene
  • N-[(4-Cyanophenyl)methyl]-1-prop-2-enoyl-N-propylpiperidine-4-carboxamide
  • 1-(prop-2-enoyl)-N-(2,4,6-trimethylphenyl)piperidine-4-carboxamide
  • N-(4-Carbamoylphenyl)-1-prop-2-enoylpiperidine-4-carboxamide
  • 4-Fluoro-N-[1-(1-prop-2-enoylpiperidine-4-carbonyl)piperidin-4-yl]benzamide
  • N-[2-Oxo-5-(trifluoromethyl)-1H-pyridin-3-yl]-1-prop-2-enoylpiperidine-4-carboxamide
  • 1-Acryloyl-N-(3-(5-methyl-1H-1,2,4-triazol-3-yl)phenyl)piperidine-4-carboxamide
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