Benzoyl bromide, 4-(bromomethyl)-

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Names

[ CAS No. ]:
876-07-3

[ Name ]:
Benzoyl bromide, 4-(bromomethyl)-

[Synonym ]:
MFCD00045026
4-BROMOMETHYLBENZOYL BROMIDE
4-Brommethyl-benzoylbromid
Benzoyl bromide,4-(bromomethyl)
p-BROMOMETHYL BENZOYL BROMIDE

Chemical & Physical Properties

[ Density]:
1.889g/cm3

[ Boiling Point ]:
100-112ºC0.5 mm Hg(lit.)

[ Melting Point ]:
57-61ºC(lit.)

[ Molecular Formula ]:
C8H6Br2O

[ Molecular Weight ]:
277.94100

[ Flash Point ]:
119.2ºC

[ Exact Mass ]:
275.87900

[ PSA ]:
17.07000

[ LogP ]:
3.11660

[ Index of Refraction ]:
1.625

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
35

[ Safety Phrases ]:
26-27-36/37/39

[ RIDADR ]:
UN 3261 8/PG 2

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • p-toluoyl chloride
  • 4-Bromomethylbenzoic acid
  • Bromine

DownStream

  • (2S)-2-amino-3-[4-[diethoxyphosphoryl(difluoro)methyl]phenyl]propanoic acid
  • Fmoc-Phe(CF2PO3)-OH
  • tert-Butyl 4-(bromomethyl)benzoate
  • [4-(bromomethyl)benzoyl] 4-(bromomethyl)benzenecarboperoxoate
  • 4-Bromomethylbenzoic acid
  • 1-(bromomethyl)-4-[diethoxyphosphoryl(difluoro)methyl]benzene
  • Ethyl 4-(bromomethyl)benzoate

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Enantioselective addition of phenylacetylene to aldehydes catalyzed by silica-immobilized titanium (IV) complex of ß-hydroxyamide. Huang LN, et al.

J. Mol. Catal. A: Chem. 275(1) , 9-13, (2007)

Systematic MALDI-TOF CID investigation on different substituted mPEG 2000. Knop K, et al.

Macromol. Chem. Phys. 211(6) , 677-684, (2010)


More Articles

Related Compounds

  • Benzoyl bromide, 4-hydroxy- (9CI)
  • Benzoyl bromide, 4-cyano- (9CI)
  • Benzoyl bromide, 4-fluoro- (9CI)
  • 4-Iodobenzyl bromide
  • [4-(bromomethyl)benzoyl] 4-(bromomethyl)benzenecarboperoxoate
  • 3-fluoro-4-methylbenzyl bromide
  • 2-[2-Fluoroethyl-(2,2,2-trifluoroacetyl)amino]-4-(4-methylpiperazin-1-yl)benzoic acid
  • N-(4-Amino-6-bromo-3-pyridinyl)-Na(2)-(2-chloro-6-fluorophenyl)-N-methylthiourea
  • 5-Bromo-6-methoxy-2-(methylthio)-4-pyrimidinamine
  • Tert-butyl 6-amino-5-methyl-2,3-dihydroindole-1-carboxylate
  • [5-(4-Hydroxy-2,6,6-trimethyl-3-oxo-1-cyclohexen-1-yl)-3-methyl-2,4-pentadien-1-yl]triphenylphosphonium bromide
  • 9-Chloro-1-methyl-7-pyridin-3-yl-4,5-dihydro-[1,2,4]triazolo[4,3-a]quinoline
  • 3-Amino-1-(5-chloro-2-methoxyphenyl)propan-1-one
  • 1-Cyclopropyl-7-pyridin-3-yl-4,5-dihydro-[1,2,4]triazolo[4,3-a]quinoline
  • 3-Bromo-5,6,7,8-tetrahydro-[1,2,4]triazolo[4,3-a]pyridine-6-carboxylic acid
  • 1-(difluoromethyl)-1H-imidazole-2-carbonitrile