Benzoyl bromide, 4-(bromomethyl)-

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Names

[ CAS No. ]:
876-07-3

[ Name ]:
Benzoyl bromide, 4-(bromomethyl)-

[Synonym ]:
MFCD00045026
4-BROMOMETHYLBENZOYL BROMIDE
4-Brommethyl-benzoylbromid
Benzoyl bromide,4-(bromomethyl)
p-BROMOMETHYL BENZOYL BROMIDE

Chemical & Physical Properties

[ Density]:
1.889g/cm3

[ Boiling Point ]:
100-112ºC0.5 mm Hg(lit.)

[ Melting Point ]:
57-61ºC(lit.)

[ Molecular Formula ]:
C₈H₆Br₂O

[ Molecular Weight ]:
277.94100

[ Flash Point ]:
119.2ºC

[ Exact Mass ]:
275.87900

[ PSA ]:
17.07000

[ LogP ]:
3.11660

[ Index of Refraction ]:
1.625

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
35

[ Safety Phrases ]:
26-27-36/37/39

[ RIDADR ]:
UN 3261 8/PG 2

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

p-toluoyl chloride
4-Bromomethylbenzoic acid
Bromine

DownStream

(2S)-2-amino-3-[4-[diethoxyphosphoryl(difluoro)methyl]phenyl]propanoic acid
Fmoc-Phe(CF2PO3)-OH
tert-Butyl 4-(bromomethyl)benzoate
[4-(bromomethyl)benzoyl] 4-(bromomethyl)benzenecarboperoxoate
4-Bromomethylbenzoic acid
1-(bromomethyl)-4-[diethoxyphosphoryl(difluoro)methyl]benzene
Ethyl 4-(bromomethyl)benzoate

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Enantioselective addition of phenylacetylene to aldehydes catalyzed by silica-immobilized titanium (IV) complex of ß-hydroxyamide. Huang LN, et al.

J. Mol. Catal. A: Chem. 275(1) , 9-13, (2007)

Systematic MALDI-TOF CID investigation on different substituted mPEG 2000. Knop K, et al.

Macromol. Chem. Phys. 211(6) , 677-684, (2010)

Benzoyl bromide, 4-hydroxy- (9CI)
Benzoyl bromide, 4-cyano- (9CI)
Benzoyl bromide, 4-fluoro- (9CI)
4-Iodobenzyl bromide
[4-(bromomethyl)benzoyl] 4-(bromomethyl)benzenecarboperoxoate
3-fluoro-4-methylbenzyl bromide
tert-Butyl (3-bromo-6-chloropyrazin-2-yl)carbamate
(1-Benzyl-4-(pyridin-2-yl)piperidin-4-yl)methanamine
tert-Butyl ((1-benzyl-4-(pyridin-2-yl)piperidin-4-yl)methyl)carbamate
(R)-1-(5-Chloro-1H-indol-3-YL)-2,2,2-trifluoroethan-1-amine
N-((S)-1-(4-Methoxyphenyl)ethyl)-8-azaspiro[4.5]decan-1-amine
tert-Butyl 1-(((S)-1-(4-methoxyphenyl)ethyl)amino)-8-azaspiro[4.5]decane-8-carboxylate
tert-Butyl 4-(((S)-1-(4-methoxyphenyl)ethyl)amino)-1-oxa-8-azaspiro[4.5]decane-8-carboxylate
N-((S)-1-(4-Methoxyphenyl)ethyl)-1-oxa-8-azaspiro[4.5]decan-4-amine
Ethyl 1-cyclopropyl-1H-pyrrole-3-carboxylate
8-Methyl-3-(trifluoromethyl)-[1,2,4]triazolo[4,3-b]pyridazin-6-amine

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