Lamprecid

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Names

[ CAS No. ]:
88-30-2

[ Name ]:
Lamprecid

[Synonym ]:
m-Cresol, α,α,α-trifluoro-4-nitro-
α,α,α-Trifluoro-4-nitro-m-cresol
WNR DQ BXFFF
3-06-00-01328 (Beilstein Handbook Reference)
EINECS 201-818-2
MFCD00014714
Phenol, 4-nitro-3-(trifluoromethyl)-
5-Hydroxy-2-nitrobenzotrifluoride
Lamprecid
Lamprecide
4-Nitro-3-(trifluoromethyl)phenol
Lamprecid 2770

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
307.5±42.0 °C at 760 mmHg

[ Melting Point ]:
76-79 °C(lit.)

[ Molecular Formula ]:
C7H4F3NO3

[ Molecular Weight ]:
207.107

[ Flash Point ]:
139.8±27.9 °C

[ Exact Mass ]:
207.014328

[ PSA ]:
66.05000

[ LogP ]:
3.10

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.507

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GP3520000
CHEMICAL NAME :
m-Cresol, alpha,alpha,alpha-trifluoro-4-nitro-
CAS REGISTRY NUMBER :
88-30-2
BEILSTEIN REFERENCE NO. :
2053698
LAST UPDATED :
199710
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C7-H4-F3-N-O3
MOLECULAR WEIGHT :
207.12
WISWESSER LINE NOTATION :
WNR DQ BXFFF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
40 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,216,1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
25 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
86 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
11FYAN "Fluorine Chemistry, Volume III. Biological Effects of Organic Fluorides," Simons, J.H., ed., New York, Academic Press, Inc., 1963 Volume(issue)/page/year: 3,84,1963
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969 Volume(issue)/page/year: 5,89,1976 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H315-H319-H332-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;Xi: Irritant;

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S26-S28-S36/37/39-S45

[ RIDADR ]:
2588

[ WGK Germany ]:
3

[ RTECS ]:
GP3520000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2908999090

Synthetic Route

Precursor & DownStream

Precursor

  • 1-Nitro-2-(trifluoromethyl)benzene
  • 3-(Trifluoromethyl)phenol
  • 3-(trifluoromethyl)acetanilide
  • 5-Amino-2-nitrobenzotrifluoride

DownStream

  • 4-Methoxy-2-(trifluoromethyl)aniline
  • 4-Methoxy-1-nitro-2-(trifluoromethyl)benzene
  • 2-Hydroxyflutamide
  • 4-Amino-3-(trifluoromethyl)phenol
  • 2-[4-nitro-3-(trifluoromethyl)phenoxy]acetic acid
  • 2-methyl-2-[4-nitro-3-(trifluoromethyl)phenoxy]propanoic acid
  • 2-methyl-2-[4-nitro-3-(trifluoromethyl)phenoxy]propanamide
  • 2-(Trifluoromethyl)-1,4-benzoquinone

Customs

[ HS Code ]: 2908999090

[ Summary ]:
2908999090 halogenated, sulphonated, nitrated or nitrosated derivatives of phenols or phenol-alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

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  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine