2-Nitroaniline

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Names

[ CAS No. ]:
88-74-4

[ Name ]:
2-Nitroaniline

[Synonym ]:
1-amino-2-nitro-benzene
Nitroaniline
Devol Orange B
EINECS 201-855-4
Benzenamine, 2-nitro-
Azoic Diazo Component 6
aniline, 2-nitro-
MFCD00007687
aniline, nitro-
o-Nitraniline
1-nitro-2-aminobenzene
2-nitrophenylamine
2-Aminonitrobenzene
1-Amino-2-nitrobenzene
Benzenamine,2-nitro
ortho-nitro-aniline
2-Nitrobenzenamine
o-nitroaniline
2-nitro-aniline

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
284.9±13.0 °C at 760 mmHg

[ Melting Point ]:
70-73 °C(lit.)

[ Molecular Formula ]:
C6H6N2O2

[ Molecular Weight ]:
138.124

[ Flash Point ]:
126.1±19.8 °C

[ Exact Mass ]:
138.042923

[ PSA ]:
71.84000

[ LogP ]:
1.83

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.634

[ Water Solubility ]:
1.1 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BY6650000
CHEMICAL NAME :
Aniline, o-nitro-
CAS REGISTRY NUMBER :
88-74-4
LAST UPDATED :
199710
DATA ITEMS CITED :
20
MOLECULAR FORMULA :
C6-H6-N2-O2
MOLECULAR WEIGHT :
138.14
WISWESSER LINE NOTATION :
ZR BNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1070 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
2350 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
750 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
9441 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - wild bird species
DOSE/DURATION :
750 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
Micronucleus test

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
10 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 320,273,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.5 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84091 No. of Facilities: 28 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 336 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84091 No. of Facilities: 54 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 1612 (estimated) No. of Female Employees: 455 (estimated)

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H331-H373-H412

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R23/24/25;R33;R52/53

[ Safety Phrases ]:
S28-S36/37-S45-S61-S28A-S16-S7

[ RIDADR ]:
UN 1661 6.1/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
BY6650000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2921420090

Synthetic Route

Precursor & DownStream

Precursor

  • 1-Iodo-2-nitrobenzene
  • 2-(2-nitrophenoxy)propanamide
  • 1-Bromo-2-nitrobenzene
  • 1,2-Dinitrobenzene
  • 2-Nitrochlorobenzene
  • o-Nitrophenol
  • Benzene,1-azido-2-nitro-
  • o-Phenylenediamine
  • 2-(trimethylsilanyl)ethanesulfonic acid (2-nitrophenyl)amide

DownStream

  • 2-(2-Chlorophenyl)benzimidazole
  • 2-(2-chlorophenyl)-1-[(2-chlorophenyl)methyl]benzimidazole
  • N-(2-nitrophenyl)-2-(4-oxoquinazolin-3-yl)acetamide
  • N-(2-nitrophenyl)-N-prop-2-enylacetamide
  • 5-[(2-nitrophenyl)hydrazinylidene]-1,3-diazinane-2,4,6-trione
  • 5-NITRO-2-(4-(5-NITRO-1H-BENZO[D]IMIDAZOL-2-YL)PHENYL)-1H-BENZO[D]IMIDAZOLE
  • 2-Nitrophenyl isocyanate
  • 2-isopropyl-1H-benzo[d]imidazole
  • 1-(2-NITRO-PHENYL)-3-PHENYL-PIPERAZINE
  • 1-(2-Nitrophenyl)pyrrolidine

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • 2-nitroaniline-ul-14c
  • 4-Iodo-2-nitroaniline
  • 5-Iodo-2-nitroaniline
  • 4-azido-2-nitroaniline
  • 5-Bromo-2-nitroaniline
  • 4-Mesyl-2-nitroaniline
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 5-Chloromethyl-3-methyl-isoxazole-4-carboxylic acid ethyl ester
  • (4-Bromo-2,5-dimethoxyphenyl)trimethylsilane
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • N-(3,4-dichlorophenyl)-1-methyl-2-oxo-2,4,5,6-tetrahydro-1H-pyrrolo[3,2,1-ij]quinoline-8-sulfonamide