((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate (R,R)-[COD]Ir[Ph2P

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Names

[ CAS No. ]:
880262-16-8

[ Name ]:
((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate (R,R)-[COD]Ir[Ph2P

Chemical & Physical Properties

[ Molecular Formula ]:
C77H58BF24IrNO3P

[ Molecular Weight ]:
1735.25000

[ Exact Mass ]:
1735.35000

[ PSA ]:
57.70000

[ LogP ]:
20.71320

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

Articles

A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes We thank Dr. Martin Studer and Dr. Beno_t Pugin (Solvias AG, Basel) for fruitful discussions, and Prof. Kevin Burgess (Texas A&M University) for preprints of related unpublished work. Financial support by the Swiss National Science Foundation is gratefully acknowledged.

Angew. Chem. Int. Ed. Engl. 40 , 4445-4447, (2001)

Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation. Menges, F. and Pfaltz, A.

Adv. Synth. Catal. 344 , 40-44, (2002)


More Articles


Related Compounds

  • 3-Benzyloxy-2-methyl-4-pyridone
  • 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}(4-fluorophenyl)amino)acetic acid
  • 6-chloro-N-(2-phenylethyl)pyrazolo[1,5-a]pyridine-2-carboxamide
  • N-benzyl-N-ethylazetidine-3-carboxamide
  • 1-(Cyclopropylmethyl)-3-(propan-2-yl)urea
  • 5-(4-(benzyloxy)phenyl)-1-(2,4-dichlorophenyl)-4-methyl-N-morpholino-1H-pyrazole-3-carboxamide
  • (2-Methyl-3-oxoisoindolin-5-yl)boronicacid
  • 7-methoxy-2,3,4,5-tetrahydro-1H-1-benzazepine-2-carboxylic acid
  • 1-[(2-Methyl-1,3-thiazol-4-yl)methyl]cyclobutan-1-amine
  • 2-(Propan-2-yloxy)cyclobutan-1-ol
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