1-METHOXY-2-NAPHTHOIC ACID

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Names

[ CAS No. ]:
883-21-6

[ Name ]:
1-METHOXY-2-NAPHTHOIC ACID

[Synonym ]:
1-methoxy-2-naphthalene carboxylic acid
2-methoxy-1-naphthoic acid
1-methoxy naphthalene-2-carboxylic acid
MFCD00094169
1-Methoxy-naphthoic acid
1-Methoxy-2-naphthoic acid

Chemical & Physical Properties

[ Density]:
1.263g/cm3

[ Boiling Point ]:
358.8ºC at 760 mmHg

[ Melting Point ]:
125-129ºC(lit.)

[ Molecular Formula ]:
C12H10O3

[ Molecular Weight ]:
202.20600

[ Flash Point ]:
142.1ºC

[ Exact Mass ]:
202.06300

[ PSA ]:
46.53000

[ LogP ]:
2.54660

[ Index of Refraction ]:
1.64

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2918990090

Synthetic Route

Precursor & DownStream

Precursor

  • Carbon dioxide
  • 1-Methoxynapthalene
  • Methyl 1-methoxy-2-naphthoate
  • 3-ethylpentan-3-yl 1-methoxy-2-naphthoate
  • 1-Methoxynaphthalene-2-carboxaldehyde
  • 1-methoxy-2-naphthoyl chloride
  • Dimethyl sulfate
  • 2-carboxy-1-naphthol
  • 1-Hydroxy-2-carboamino Naphthalene Derivative

DownStream

  • 1,4-Dihydro-2-naphthoic acid
  • 1,2,3,4-Tetrahydro-2-naphthoic acid
  • 2-Naphthoic acid
  • 2-methyl-1,2,3,4-tetrahydro-2-naphthoic acid
  • 1,2,3,4,5,6,7,8-OCTAHYDRO-NAPHTHALENE-2-CARBOXYLIC ACID
  • propan-2-yl 1-methoxynaphthalene-2-carboxylate
  • (S)-(-)-1,1'-Bi-2-naphthol
  • 1-METHOXY-2-NAPHTHALENEMETHANOL
  • 1-methoxynaphthalene-2-carboxamide

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

The trifluoromethoxy group: a long-range electron-withdrawing substituent.

Chemistry 8(4) , 799-804, (2002)

Judged by its capacity to promote a hydrogen/metal permutation at an ortho position, the trifluoromethoxy group is superior to both the methoxy and trifluoromethyl groups. Moreover, like CF(3) and unl...

ortho-Lithium/magnesium carboxylate-driven aromatic nucleophilic substitution reactions on unprotected naphthoic acids.

J. Org. Chem. 77(1) , 718-24, (2012)

Substitution of an ortho-fluoro or methoxy group in 1- and 2-naphthoic acids furnishing substituted naphthoic acids occurs in good to excellent yields upon reaction with alkyl/vinyl/aryl organolithium...

Birch Reduction of 2-Naphthoic and of ortho-Methoxynaphthoic Acids. Eliel EL and Hoover TE.

J. Org. Chem. 24(7) , 938-942, (1959)


More Articles


Related Compounds

  • 4-bromo-1-methoxy-2-naphthoic acid
  • 1-methoxy-2-naphthoic acid chloride
  • 4-formyl-1-methoxy-2-naphthoic acid
  • 1-methoxy-2-naphthoic acid methyl ester
  • 1-methoxy-4-(4-methoxybenzyl)-2-naphthoic acid
  • 1-hydroxy-4-methoxy-[2]naphthoic acid ethyl ester
  • 5-(azidomethyl)-1-isobutyl-3-(trifluoromethyl)-1H-pyrazole
  • 5-(azidomethyl)-1-(2-fluoroethyl)-3-(trifluoromethyl)-1H-pyrazole
  • 5-(azidomethyl)-1-(prop-2-yn-1-yl)-3-(trifluoromethyl)-1H-pyrazole
  • 2-(5-(azidomethyl)-3-(trifluoromethyl)-1H-pyrazol-1-yl)acetonitrile
  • [(1-ethyl-5-fluoro-1H-pyrazol-4-yl)methyl][(oxolan-2-yl)methyl]amine
  • [(1-ethyl-5-fluoro-1H-pyrazol-4-yl)methyl](hexyl)amine
  • [3-(dimethylamino)propyl][(1-ethyl-5-fluoro-1H-pyrazol-4-yl)methyl]amine
  • 5-(azidomethyl)-1-(difluoromethyl)-3-(trifluoromethyl)-1H-pyrazole
  • 2-(1-isopropyl-3-(trifluoromethyl)-1H-pyrazol-5-yl)acetonitrile
  • 2-(1-(cyclopropylmethyl)-3-(trifluoromethyl)-1H-pyrazol-5-yl)acetonitrile
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