Methyl 2-hydroxy-3-naphthoate

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Names

[ CAS No. ]:
883-99-8

[ Name ]:
Methyl 2-hydroxy-3-naphthoate

[Synonym ]:
MFCD00004099
Methyl 3-hydroxy-2-naphthoate
methyl 3-hydroxynaphthalene-2-carboxylate
EINECS 212-936-9
2-Hydroxy-3-naphthoic acid methyl ester
Methyl 2-hydroxy-3-naphthoate
2-Naphthalenecarboxylic acid, 3-hydroxy-, methyl ester
2-Naphthoic acid, 3-hydroxy-, methyl ester
2-Naphthoic acid, 3-hydroxy-, methyl ester (8CI)
Methyl 3-hydroxy-2-naphthalenecarboxylate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
330.5±15.0 °C at 760 mmHg

[ Melting Point ]:
73-75 °C(lit.)

[ Molecular Formula ]:
C₁₂H₁₀O₃

[ Molecular Weight ]:
202.206

[ Flash Point ]:
142.5±13.2 °C

[ Exact Mass ]:
202.062988

[ PSA ]:
46.53000

[ LogP ]:
3.46

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.642

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ HS Code ]:
2918290000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Methanol
3-Hydroxy-2-naphthoic acid
methyl 3-[2-(2-methoxy-2-oxoethyl)phenyl]prop-2-ynoate
methyl iodide
Dimethyl sulfate
tert-Butyl Hydroperoxide
methyl 3-methoxymethoxy-2-naphthoate
naphtho[2,3-b]oxet-2-one
Ethanol
2-Naphthalenecarboxylicacid, 3-(acetyloxy)-

DownStream

2-Naphthalenamine,3-methyl-
1-AMINO-2-HYDROXY-NAPHTALENE-3-CARBOXYLIC ACID METHYL ESTER
3-Hydroxy-2-naphthohydrazide
2-Naphthalenemethanol,3-methoxy-
methyl 3-hydroxy-4-nitrosonaphthalene-2-carboxylate
7H-Dibenzo[c,g]carbazole
UNII:TL35μ1249
3-HYDROXY-2-NAPHTHOHYDROXAMICACID

Customs

[ HS Code ]: 2918290000

[ Summary ]:
HS: 2918290000 other carboxylic acids with phenol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) VAT:17.0% MFN tariff:6.5% General tariff:30.0%

Articles

Enantioselective oxidative coupling of methyl 3-hydroxy-2-naphthoate using mono-< i> N</i>-alkylated octahydrobinaphthyl-2, 2'-diamine ligand. Kim KH, et al.

Tetrahedron 60(41) , 9037-42, (2004)

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