phenylallylchloro-[1,3-bis(diisopropylphenyl)imidazole-2-ylidene]palladium(ii)

[ Molecular Formula ]:
C₃₆H₄₅ClN₂Pd

[ Molecular Weight ]:
647.62900

[ Exact Mass ]:
646.23100

[ PSA ]:
9.86000

[ LogP ]:
10.84780

[ Storage condition ]:
-20°C

Click to get detail MSDS

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H315-H319-H332

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
20/21/22-36/38

[ Safety Phrases ]:
22-24/25-26-36/37

[ RIDADR ]:
NONH for all modes of transport

Room-temperature Suzuki-Miyaura couplings in water facilitated by nonionic amphiphiles.

Org. Lett. 10 , 1333, (2008)

Use of a dilute aqueous solution containing a nonionic amphiphile allows efficient Suzuki-Miyaura cross-couplings of arylboronic acids with a wide array of aryl halides and pseudohalides, including st...

Modified (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes for room-temperature Suzuki-Miyaura and Buchwald-Hartwig reactions.

J. Am. Chem. Soc. 128 , 4101, (2006)

A series of (NHC)Pd(R-allyl)Cl complexes [NHC: IPr = N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, SIPr = N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene; R = H, Me, gem-Me2, Ph] ha...

Rapid room temperature Buchwald-Hartwig and Suzuki-Miyaura couplings of heteroaromatic compounds employing low catalyst loadings.

Chemistry 12 , 5142, (2006)

The use of second-generation [(NHC)Pd(R-allyl)Cl] complexes for Suzuki-Miyaura and Buchwald-Hartwig cross-coupling reactions involving heteroaromatic halides at room temperature is reported. The first...

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