TERT-BUTYL(4-CHLOROBUTOXY)DIMETHYLSILANE

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Names

[ Name ]:
TERT-BUTYL(4-CHLOROBUTOXY)DIMETHYLSILANE

[Synonym ]:
4-tert-butyldimethylsilyloxy-1-chlorobutane
MFCD00239391
Silane,(4-chlorobutoxy)(1,1-dimethylethyl)dimethyl
4-chlorobutyl t-butyldimethylsilyl ether
3-chlorobutanol-TBS ether
tert-butyl-(4-chlorobutoxy)dimethylsilane
1-(tert-butyldimethylsilyloxy)-4-chloro-butane

Chemical & Physical Properties

[ Density]:
0.87 g/mL at 25ºC(lit.)

[ Boiling Point ]:
201ºC(lit.)

[ Molecular Formula ]:
C₁₀H₂₃ClOSi

[ Molecular Weight ]:
222.82800

[ Flash Point ]:
179 °F

[ Exact Mass ]:
222.12100

[ PSA ]:
9.23000

[ LogP ]:
4.02720

[ Index of Refraction ]:
n20/D 1.439(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

4-Chloro-1-butanol
tert-Butyldimethylsilyl chloride
4-tert-Butyldimethylsiloxy-1-butanol
Imidazole
tert-Butyldimethylsilyl Trifluoromethanesulfonate

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Samarium(II) iodide-mediated intramolecular conjugate additions of alpha,beta-unsaturated lactones.

J. Org. Chem. 67(11) , 3861-5, (2002)

Samarium(II) iodide, in the presence of catalytic amounts of nickel(II) iodide, has been used to promote intramolecular conjugate additions of alkyl halides onto alpha,beta-unsaturated lactones. This ...

tert-butyl-(4-chlorophenoxy)-dimethylsilane
tert-butyl-(4-iodobutoxy)-dimethylsilane
TERT-BUTYL(4-FLUOROPHENOXY)DIMETHYLSILANE
tert-Butyl(4-ethynylphenoxy)dimethylsilane
tert-butyl-(4-methylbenzyloxy)dimethylsilane
tert-butyl((4-iodophenyl)ethynyl)dimethylsilane
3-(3-Methoxyphenoxy)azetidine hydrochloride
Methyl 4-{[3-(3-cyclopropyl-1,2,4-oxadiazol-5-yl)-7-methyl-1,8-naphthyridin-4-yl]amino}benzoate
1-[3-(3-ethyl-1,2,4-oxadiazol-5-yl)pyridin-2-yl]-N-(4-methoxyphenyl)-1H-imidazole-4-carboxamide
1-{5-[3-(tert-butyl)-1,2,4-oxadiazol-5-yl]-2-pyridyl}-N~4~-(4-fluorobenzyl)-1H-imidazole-4-carboxamide
O-(4-Methylphenyl)-L-homoserine
1,4-Bis-{[2-(2-hydroxymethylpiperidine-1-yl)ethyl]amino}-5,8-dihydroxy-anthracene-9,10-dione
I+/--(4-Chlorophenyl)-3,5-dimethylbenzenemethanamine
1-(4-Chlorophenyl)-3,3-dimethylbutan-1-amine
(5-Chloro-2-methoxyphenyl)(4-chlorophenyl)methanamine
N-hydroxy-5-(1-methyl-3-(trifluoromethyl)-1H-pyrazol-5-yl)thiophene-2-carboxamide

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