(3-Bromophenyl)boronic acid

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Names

[ CAS No. ]:
89598-96-9

[ Name ]:
(3-Bromophenyl)boronic acid

[Synonym ]:
(3-Bromophenyl)boronic acid
Boronic acid, B-(3-bromophenyl)-
MFCD00239386

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
330.5±44.0 °C at 760 mmHg

[ Melting Point ]:
164-168 °C(lit.)

[ Molecular Formula ]:
C6H6BBrO2

[ Molecular Weight ]:
200.83

[ Flash Point ]:
153.7±28.4 °C

[ Exact Mass ]:
199.964417

[ PSA ]:
40.46000

[ LogP ]:
2.36

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.598

[ Storage condition ]:
0-6°C

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Precursor & DownStream

Precursor

  • BUTYL BORATE

DownStream

  • 3-Bromophenyl methyl sulfone
  • 2-(3-Bromophenyl)-1H-imidazole
  • 2-(3-Bromophenyl)pyridine
  • 1-Azido-3-bromobenzene
  • 1-Benzyl-3-bromobenzene
  • methyl 3,3-bis(3-bromophenyl)propanoate
  • (E)-METHYL 3-(3-BROMOPHENYL)ACRYLATE
  • 2-(3-bromophenyl)furan
  • 2-(3-Bromophenyl)naphthalene
  • 3-Bromoaniline

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

ipso-nitration of arylboronic acids with chlorotrimethylsilane-nitrate salts.

Org. Lett. 6 , 2205-2207, (2004)

[reaction: see text] A mixture of nitrate salt and chlorotrimethylsilane is found to be an efficient regioselective nitrating agent for the ipso-nitration of arylboronic acids to produce the correspon...


More Articles


Related Compounds

  • (3-(BENZYLOXY)-5-BROMOPHENYL)BORONIC ACID
  • PYRIDINE-3-BORONIC ACID HYDROCHLORIDE
  • DIBENZOTHIOPHENE-3-BORONIC ACID
  • Benzothiophene-3-boronic acid
  • Pyridazine-3-boronic acid pinacol ester
  • Pyrazole-3-boronic Acid Hydrate
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  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine