5-Chloro-2-methoxyphenylboronic acid

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Names

[ CAS No. ]:
89694-48-4

[ Name ]:
5-Chloro-2-methoxyphenylboronic acid

[Synonym ]:
MFCD01318966
(5-Chloro-2-methoxyphenyl)boronic acid
Boronic acid, B-(5-chloro-2-methoxyphenyl)-

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
360.2±52.0 °C at 760 mmHg

[ Melting Point ]:
134-141 °C(lit.)

[ Molecular Formula ]:
C7H8BClO3

[ Molecular Weight ]:
186.401

[ Flash Point ]:
171.6±30.7 °C

[ Exact Mass ]:
186.025497

[ PSA ]:
49.69000

[ LogP ]:
2.19

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.545

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Trimethyl borate
  • 2-Bromo-4-chloro-1-methoxybenzene
  • 2-Methoxyphenylboronic acid
  • Triisopropylborate
  • BUTYL BORATE

DownStream

  • 5-chloro-2-methoxyphenol
  • (5-Chloro-2-hydroxyphenyl)boronic acid
  • 3-(5-chloro-2-methoxyphenyl)pyridine-4-carboxylic acid
  • 4-chloro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
  • 2-(2-bromocyclopenten-1-yl)-4-chloro-1-methoxybenzene
  • 2-chlorobenzo[c]chromen-6-one
  • 2-(5-chloro-2-methoxyphenyl)-1H-benzimidazole

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • 5-Chloro-2-methoxyphenylboronic acid pinacol ester
  • 5-Chloro-2-fluoro-4-methoxyphenylboronic acid
  • 5-chloro-2-fluoro-4-methoxyphenylboronic acid
  • 5-Chloro-2-fluoro-4-methoxyphenylboronic acid pinacol ester
  • 4-Chloro-2-methoxyphenylboronic acid
  • 5-CHLORO-2-ETHOXYPHENYLBORONIC ACID
  • 2-(7-chloro-6-methyl-10-oxo-3,4-dihydrobenzo[b][1,6]naphthyridin-2(1H,5H,10H)-yl)-N-(4-fluorophenyl)acetamide
  • N-isobutyl-3-[4-(3-methoxyphenoxy)pyrimidin-2-yl]benzamide
  • N-(3-chloro-4-methoxyphenyl)-2-[2-(5-phenyl-1,3,4-oxadiazol-2-yl)-1H-pyrrol-1-yl]acetamide
  • 2-(Butan-2-yloxy)-4-fluoroaniline
  • N-allyl-2-(3-{[(3,4-dimethoxyphenyl)sulfonyl]amino}phenoxy)nicotinamide
  • 2-(7-chloro-6-methyl-10-oxo-1,3,4,5-tetrahydrobenzo[b][1,6]naphthyridin-2-yl)-N-(2,4-difluorophenyl)acetamide
  • 2-(7-chloro-6-methyl-10-oxo-3,4-dihydrobenzo[b][1,6]naphthyridin-2(1H,5H,10H)-yl)-N-(2-fluorophenyl)acetamide
  • 1-(4-{[(4-fluorophenyl)sulfonyl]amino}benzoyl)-N-(tetrahydrofuran-2-ylmethyl)piperidine-4-carboxamide
  • 2-(7-chloro-6-methyl-10-oxo-3,4-dihydrobenzo[b][1,6]naphthyridin-2(1H,5H,10H)-yl)-N-(3,5-dimethylphenyl)acetamide
  • 2-(7-chloro-6-methyl-10-oxo-3,4-dihydrobenzo[b][1,6]naphthyridin-2(1H,5H,10H)-yl)-N-(3-(methylthio)phenyl)acetamide
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