Metiram

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Names

[ CAS No. ]:
9006-42-2

[ Name ]:
Metiram

[Synonym ]:
MFCD00166315
zinc,N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate
Zinc ethylenebisdithiocarbamate
Dithane Z-78
Novozir
Cynkotox
Parzate
Zinc ethylenebisthiocarbamate
zinc ethane-1,2-diylbis(dithiocarbamate)

Chemical & Physical Properties

[ Boiling Point ]:
308.2ºC at 760mmHg

[ Melting Point ]:
157ºC (decomposes)

[ Molecular Formula ]:
C4H6N2S4Zn

[ Molecular Weight ]:
275.74400

[ Flash Point ]:
140.2ºC

[ Exact Mass ]:
273.87100

[ PSA ]:
102.32000

[ LogP ]:
0.64930

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TR6250000
CHEMICAL NAME :
Polyram
CAS REGISTRY NUMBER :
9006-42-2
LAST UPDATED :
199506
WISWESSER LINE NOTATION :
/*-ZN-SYUS&M2MYUS&S*/ &/*SYUS&M2MYUS&S*/

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2850 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5700 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2630 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
620 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
2400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
3750 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
7660 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - domestic
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
5250 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
3290 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Gene conversion and mitotic recombination
TEST SYSTEM :
Yeast - Saccharomyces cerevisiae
DOSE/DURATION :
50 ppm
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 10,533,1970 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
UN 1282 3 / PGII

[ RTECS ]:
TR6250000

Articles

Effects of the fungicide metiram in outdoor freshwater microcosms: responses of invertebrates, primary producers and microbes.

Ecotoxicology 21(5) , 1550-69, (2012)

The ecological impact of the dithiocarbamate fungicide metiram was studied in outdoor freshwater microcosms, consisting of 14 enclosures placed in an experimental ditch. The microcosms were treated th...

Genotoxic effects of pesticides.

J. Environ. Pathol. Toxicol. Oncol. 15(2-4) , 75-8, (1996)

Epidemiologic data showed an increase in the number of cancer cases in persons involved in agricultural production using pesticides. According to IARC, more than 25% of pesticides are classified as on...

[The potential for using an integrated method of soil disinfection in microfoci of geohelminthiases].

Med. Parazitol. (Mosk.) (3) , 23-5, (1993)

Polycarbocin-lupine and polycarbocin-pea systems were found to exert a marked ovicidal effect providing decontamination of the top soil layer from ascarid eggs for 3 months. A combination of 4-5 mg of...


More Articles


Related Compounds

  • Metiram-zinc
  • {1-[(2-Chloro-5-methylphenyl)methyl]cyclopropyl}methanamine
  • rac-(1R,2S)-2-(3-chloro-2-methoxyphenyl)cyclopropan-1-amine
  • 3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4,4,4-trifluorobutanamido]oxolane-3-carboxylic acid
  • 2-{3-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]pentanamido}-4,4,4-trifluorobutanoic acid
  • 2-[N-(cyclopropylmethyl)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-(methoxymethyl)propanamido]acetic acid
  • 3,3-Difluoro-3-(quinolin-3-yl)propan-1-amine
  • (2S,4R)-1-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylbutanoyl]-4-hydroxypyrrolidine-2-carboxylic acid
  • rac-1-[(1R,2S)-2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopentanecarbonyl]-4-methylpyrrolidine-3-carboxylic acid
  • (2S,4S)-1-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)benzoyl]-4-hydroxypyrrolidine-2-carboxylic acid
  • 3-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpropanamido]-4-methylpentanoic acid
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