Lithium bis(trifluoromethanesulphonyl)imide

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Names

[ CAS No. ]:
90076-65-6

[ Name ]:
Lithium bis(trifluoromethanesulphonyl)imide

[Synonym ]:
Lithium bis(trifluoromethanesulfonyl)imide
Lithium bis[(trifluoromethyl)sulfonyl]azanide
FXFFSWMSWXFFF &&Li salt
MFCD00210017
lithium,bis(trifluoromethylsulfonyl)azanide
Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-, lithium salt (1:1)
Bis(trifluoromethane)sulfonimide lithium salt
Lithium bis(trifluoromethanesulphonyl)imide
1,1,1-Trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide lithium salt (1:1)
EINECS 415-300-0

Chemical & Physical Properties

[ Density]:
1,334 g/cm3

[ Boiling Point ]:
190.5ºC at 760 mmHg

[ Melting Point ]:
234-238 °C(lit.)

[ Molecular Formula ]:
C2F6LiNO4S2

[ Molecular Weight ]:
287.087

[ Flash Point ]:
69ºC

[ Exact Mass ]:
286.933289

[ PSA ]:
88.28000

[ LogP ]:
2.61350

[ Water Solubility ]:
H2O: 10 mg/mL, clear, colorless

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311-H314-H373-H412

[ Precautionary Statements ]:
P273-P280-P301 + P310 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R24/25;R34;R52/53

[ Safety Phrases ]:
S22-S26-S36/37/39-S45-S61

[ RIDADR ]:
UN 2923 8/PG 2

[ WGK Germany ]:
2

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2924199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • trifluoromethanesulfonyl fluoride
  • trifluoromethanesulfonimide
  • Et3NH(1+)*Tf2N(1-)

DownStream

  • N,1,1,1-tetrafluoro-N-(trifluoromethylsulfonyl)methanesulfonamide
  • Triethylsulfonium bis(trifluoromethylsulfonyl)imide
  • BMP-NTf2
  • trifluoromethanesulfonimide
  • Lithium
  • 1-Butyl-2,3-dimethylimidazolium bis(trifluoromethanesulfonyl)imide
  • 1-Butyl-3-Methylimidazolium Bis(Trifluoromesulfonyl)imide
  • 0,11-DIMETHOXY-6-METHYL-5,6-DIHYDRO-4H-DIBENZO[DE,G]QUINOLINE
  • 1-Ethyl-2,3-Dimethylimidazolium Bis(Trifluoromethanesulfonyl)Imide
  • 1-Ethyl-3-Methylimidazolium Bis(Trifluoromethylsulfonyl)Imide

Customs

[ HS Code ]: 2924199090

[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

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ACS Nano 9 , 6147-57, (2015)

This study reports on a facile approach to the fabrication of nanoporous carbon cathodes for lithium sulfur batteries using gyroid carbon replicas based on use of polystyrene-poly-4-vinylpyridine (PS-...

Preparation and evaluation of surface-bonded tricationic ionic liquid silica as stationary phases for high-performance liquid chromatography.

J. Chromatogr. A. 1396 , 62-71, (2015)

Two tricationic ionic liquids were prepared and then bonded onto the surface of supporting silica materials through "thiol-ene" click chemistry as new stationary phases for high-performance liquid chr...

Development of bipolar all-solid-state lithium battery based on quasi-solid-state electrolyte containing tetraglyme-LiTFSA equimolar complex.

Sci. Rep. 5 , 8869, (2015)

The development of high energy-density lithium-ion secondary batteries as storage batteries in vehicles is attracting increasing attention. In this study, high-voltage bipolar stacked batteries with a...


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Related Compounds

  • Lithium Bis(pentafluoroethanesulfonyl)imide
  • Lithium bis(fluorosulfonyl)azanide
  • lithium bis(1,1,2,2,3,3,3-heptafluoro-1-propanesulfonyl)imide
  • Lithium Bis(nonafluorobutanesulfonyl)imide
  • lithium bis(tert-butyl)phosphide
  • lithium,bis[dimethyl(phenyl)silyl]methyl-dimethyl-phenylsilane
  • N-(1-cyano-1,2-dimethylpropyl)-2-[(2-hydroxybutyl)(phenyl)amino]acetamide
  • 1-(4-{[(2,3-dihydro-1H-inden-1-yl)(prop-2-yn-1-yl)amino]methyl}piperidin-1-yl)ethan-1-one
  • (3S,3abeta,6abeta)-3beta-[(tert-Butoxycarbonyl)amino]hexahydro-2H-thieno[2,3-c]pyrrole 1,1-dioxide
  • 4'-Carbazol-9-yl-biphenyl-4-ol
  • N-(4-Bromophenyl)-N,9-diphenyl-9H-carbazol-3-amine
  • 1,1'-(Tetrahydro-6a-hydroxy-2,3a,5-trimethylfuro(2,3-d)-1,3-dioxole-2,5-diyl)bis-ethanone, (2R,3aS,5R,6aS)-
  • 1,1'-(Tetrahydro-6a-hydroxy-2,3a,5-trimethylfuro(2,3-d)-1,3-dioxole-2,5-diyl)bis-ethanone, (2S,3aS,5S,6aS)-
  • 1,1'-(Tetrahydro-6a-hydroxy-2,3a,5-trimethylfuro(2,3-d)-1,3-dioxole-2,5-diyl)bis-ethanone, (2R,3aS,5S,6aS)-
  • 1,1'-(Tetrahydro-6a-hydroxy-2,3a,5-trimethylfuro(2,3-d)-1,3-dioxole-2,5-diyl)bis-ethanone, (2R,3as,5R,6aR)-
  • 1,1'-(Tetrahydro-6a-hydroxy-2,3a,5-trimethylfuro(2,3-d)-1,3-dioxole-2,5-diyl)bis-ethanone, (2S,3as,5R,6aS)-
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