[Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride

Names

[ CAS No. ]:
905709-79-7

[ Name ]:
[Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride

Chemical & Physical Properties

[ Molecular Formula ]:
C49H46Cl2O2P2Ru

[ Molecular Weight ]:
900.81200

[ Exact Mass ]:
900.13900

[ PSA ]:
45.64000

[ LogP ]:
4.15770

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

Articles

Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters.

J. Org. Chem. 65 , 6223, (2000)

Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates.

J. Am. Chem. Soc. 125 , 9570, (2003)

Hydrogenation of a series of cyclic beta-(acylamino)acrylates with tetrasubstituted olefins has been accomplished successfully with the use of Ru catalysts with chiral biaryl ligands such as C3-TunaPh...

Highly enantioselective asymmetric hydrogenation of alpha-phthalimide ketone: an efficient entry to enantiomerically pure amino alcohols.

J. Am. Chem. Soc. 126 , 1626, (2004)

A new type of alpha-phthalimide ketones was hydrogenated in excellent enantioselectivity by using a Ru-(C3-TunePhos) complex as the catalyst. Up to 10 000 turnovers have been achieved in more than 99%...


More Articles

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