leucoline

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Names

[ CAS No. ]:
91-22-5

[ Name ]:
leucoline

[Synonym ]:
1-Azanaphthalene
Chinolin
EINECS 202-051-6
1-Benzazine
Quinolin
Chinoline
leucoline
Leucol
β-Quinoline
Quinoline
MFCD00006736
Chinoleine
Benzopyridine
Fasudil Impurity 8

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
234.1±9.0 °C at 760 mmHg

[ Melting Point ]:
−17-−13 °C(lit.)

[ Molecular Formula ]:
C9H7N

[ Molecular Weight ]:
129.159

[ Flash Point ]:
101.1±0.0 °C

[ Exact Mass ]:
129.057846

[ PSA ]:
12.89000

[ LogP ]:
2.08

[ Vapour density ]:
4.5 (vs air)

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.642

[ Stability ]:
Stable. Incompatible with strong acids, strong oxidizing agents. May discolour on exposure to light. Hygroscopic - protect from moisture. Reacts violently and unpredictably with some materials, especially strong oxidizing agents.

[ Water Solubility ]:
slightly soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VA9275000
CHEMICAL NAME :
Quinoline
CAS REGISTRY NUMBER :
91-22-5
LAST UPDATED :
199806
DATA ITEMS CITED :
32
MOLECULAR FORMULA :
C9-H7-N
MOLECULAR WEIGHT :
129.17
WISWESSER LINE NOTATION :
T66 BNJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
331 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
540 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Amphibian - frog
DOSE/DURATION :
150 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7770 mg/kg/37W-C
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Liver - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
50 gm/kg/30W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
9042 ug/kg/15D-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Blood - lymphoma, including Hodgkin's disease
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
23 gm/kg/30W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors
TYPE OF TEST :
Micronucleus test
TYPE OF TEST :
Mutation in mammalian somatic cells

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
110 ug/L
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 7,1,1985 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84566 No. of Facilities: 258 (estimated) No. of Industries: 7 No. of Occupations: 7 No. of Employees: 29238 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84566 No. of Facilities: 456 (estimated) No. of Industries: 9 No. of Occupations: 16 No. of Employees: 4241 (estimated) No. of Female Employees: 810 (estimated)

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H312-H315-H319-H341-H350-H411

[ Precautionary Statements ]:
P201-P273-P280-P301 + P310-P305 + P351 + P338-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R21/22;R37/38;R40;R41;R68

[ Safety Phrases ]:
S26-S36/37/39-S36-S23

[ RIDADR ]:
UN 2656 6.1/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
VA9275000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2933499090

Synthetic Route

Precursor & DownStream

Precursor

  • 1,2,3,4-Tetrahydroquinoline
  • Benzenamine,N-2-propyn-1-yl-
  • 8-Hydroxyquinoline
  • Formaldehyde
  • Benzenamine, 2-ethenyl-
  • Quinoline-2-carboxylic acid
  • nitrobenzene
  • Glycerol
  • Quinoline-4-carbaldehyde

DownStream

  • Ethanone,1-(9H-carbazol-9-yl)-
  • 2-(2,5-dimethyl-phenyl)-quinoline
  • 2,2',5,5'-Tetramethylbiphenyl
  • 2-(2,5-dimethylphenyl)-1,2-dihydroquinoline
  • (E)-3-Methyl-1,3-pentadiene
  • 3-Methyl-2-furoic acid
  • 3-Chloroquinoline
  • 1-(Quinolin-2-yl)ethanone
  • 1-(QUINOLIN-4-YL)ETHANONE
  • 1-(2-acetylquinolin-4-yl)ethanone

Customs

[ HS Code ]: 2933499090

[ Summary ]:
2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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Related Compounds

  • LEUCOLINE
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 6-Fluoro-5-hydroxynicotinaldehyde
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • (4-Aminocyclohexyl)urea dihydrochloride
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (1S)-1-Methylpropyl (I+/-S)-I+/--methyl-4-(2-methylpropyl)benzeneacetate
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde