2-Methylnaphthalene

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Names

[ CAS No. ]:
91-57-6

[ Name ]:
2-Methylnaphthalene

[Synonym ]:
2-METHYL NAPHTHALENE
beta-Methylnaphthalene
2-methyl-1-naphtoic acid
2-Methylnaphthalen-1-carbonsaeure
2-methyl-naphthalene
B-METHYLNAPHTHALENE
EINECS 202-078-3
L66J B1
2-methyl-1-naphthoic acid
2-metylnaphtalene
2-METHYLNAPHTHALENE FOR SYNTHESIS
2-Methylnaphthalen
2-Methylnaphthalene
2-methyl-1-naphthalenecarboxylic acid
2-methylnaphtalene
2-methylnaphthoic acid
MFCD00004118
2-METHYLNAPTHALENE
β-Methylnaphthalene
Naphthalene, 2-methyl-
SS-METHYLNAPHTHALENE
Fasudil Impurity 13

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
239.9±3.0 °C at 760 mmHg

[ Melting Point ]:
34-36 °C(lit.)

[ Molecular Formula ]:
C11H10

[ Molecular Weight ]:
142.197

[ Flash Point ]:
97.8±0.0 °C

[ Exact Mass ]:
142.078247

[ LogP ]:
3.91

[ Vapour Pressure ]:
0.1±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.617

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
0.00246 g/100 mL

[ Freezing Point ]:
34.5℃

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QJ9635000
CHEMICAL NAME :
Naphthalene, 2-methyl-
CAS REGISTRY NUMBER :
91-57-6
LAST UPDATED :
199801
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C11-H10
MOLECULAR WEIGHT :
142.21
WISWESSER LINE NOTATION :
L66J C1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1630 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
28500 mg/kg/81W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
250 umol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 208,155,1988 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 20 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1659 No. of Facilities: 633 (estimated) No. of Industries: 10 No. of Occupations: 15 No. of Employees: 3498 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1659 No. of Facilities: 376 (estimated) No. of Industries: 5 No. of Occupations: 5 No. of Employees: 4359 (estimated) No. of Female Employees: 1608 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H301 + H311 + H331-H370

[ Precautionary Statements ]:
P210-P260-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R22;R51/53

[ Safety Phrases ]:
S26-S37/39-S61-S36/37-S24/25-S23-S53

[ RIDADR ]:
UN 3077 9/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
QJ9635000

[ Packaging Group ]:
III

[ Hazard Class ]:
9

[ HS Code ]:
29029080

Synthetic Route

Precursor & DownStream

Precursor

  • 1-Bromonaphthalene
  • METHYLLITHIUM
  • 2-Naphthalenemethanol
  • carbon monoxide
  • 3-(2-phenylethenyl)furan
  • 2-Naphthaldehyde
  • 2-(brommethyl)naphthalen
  • (2-Naphtyloxy)trimethylsilane
  • METHYLMAGNESIUM BROMIDE
  • 1-Bromo-2-methylnaphthalene

DownStream

  • 2-Naphthalenamine,3-methyl-
  • 4-(6-methylnapthalen-2-yl)-4-oxobut-2-enoc acid
  • 2-Methyl-1,2'-dinaphthyl Ketone
  • 4-Methylphthalic acid
  • Trimellitic acid
  • 2-Naphthaldehyde
  • Phthalic acid
  • benzoic acid
  • 2-Naphthoic acid
  • 2-METHYL-1-NAPHTHALDEHYDE

Customs

[ HS Code ]: 29029080

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Simplified molecular input line entry system (SMILES) has been utilized in constructing quantitative structure-property relationships (QSPR) for octanol/water partition coefficient of vitamins and org...

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Related Compounds

  • 2-Methylnaphthalene
  • 2-Methylnaphthalene
  • 2-Methylnaphthalene-d10
  • 1-Iodo-2-methylnaphthalene
  • 2-methylnaphthalene-1-amine
  • 2-methylnaphthalene-1-thiol
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • 3-Butoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-YL)pyridine