N,N-Diethylaniline

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Names

[ CAS No. ]:
91-66-7

[ Name ]:
N,N-Diethylaniline

[Synonym ]:
EINECS 202-088-8
Aniline,N,N-diethyl
N,N-diethylbenzeneamine
2N2&R
N,N-Diethylaniline
N,N-Diethylanilin
MFCD00009042
N,N-Diethylbenzenamine
Benzenamine, N,N-diethyl-
Diethylphenylamine
N,N-diethyl-aniline
Benzenamine,N,N-diethyl
Phenyldiethylamine
4-N,N-diethylaminobenzene
Diethylaniline
Diaethylanilin

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
213.5±9.0 °C at 760 mmHg

[ Melting Point ]:
-38 °C

[ Molecular Formula ]:
C10H15N

[ Molecular Weight ]:
149.233

[ Flash Point ]:
97.8±0.0 °C

[ Exact Mass ]:
149.120453

[ PSA ]:
3.24000

[ LogP ]:
3.39

[ Vapour density ]:
5.2 (vs air)

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.533

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents, strong acids.

[ Water Solubility ]:
14 g/L (12 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BX3400000
CHEMICAL NAME :
Aniline, N,N-diethyl-
CAS REGISTRY NUMBER :
91-66-7
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C10-H15-N
MOLECULAR WEIGHT :
149.26
WISWESSER LINE NOTATION :
2N2&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1920 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0282-0430
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
420 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AGGHAR Archiv fuer Gewerbepathologie und Gewerbehygiene. (Berlin, Ger.) V.1-18, 1930-61. For publisher information, see IAEHDW. Volume(issue)/page/year: 15,447,1957
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
2570 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(6),22,1983 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83987 No. of Facilities: 514 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 2387 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83987 No. of Facilities: 302 (estimated) No. of Industries: 3 No. of Occupations: 5 No. of Employees: 3640 (estimated) No. of Female Employees: 777 (estimated)

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H373-H411

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R23/24/25;R33;R51/53

[ Safety Phrases ]:
S28-S37-S45-S61-S28A

[ RIDADR ]:
UN 2432 6.1/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
BX3400000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2921420090

Synthetic Route

Precursor & DownStream

Precursor

  • Bromobenzene
  • Diethylamine
  • Iodobenzene
  • Acetonitrile
  • diethylamino benzoate
  • diphenylzinc
  • nitrobenzene
  • lithium,diethylazanide
  • Bromoethane

DownStream

  • (4-chlorophenyl)-[4-(diethylamino)phenyl]methanone
  • 6-[4-(diethylamino)phenyl]quinoline-5,8-dione
  • ethyl 4-[[4-(diethylamino)phenyl]diazenyl]benzoate
  • 4-[1-[4-(diethylamino)phenyl]ethyl]-N,N-diethylaniline
  • 4-Diethylaminoacetophenone
  • 4-Ethynyl-1,2-dimethoxybenzene
  • 4-(Diethylamino)benzoic acid
  • 2-Amino-5-methoxyphenol
  • Benzoxazole,6-methoxy-2-methyl-
  • 1,3-Dichloro-4,6-dinitrobenzene

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • boron,N,N-diethylaniline
  • 4-Iodo-N,N-diethylaniline
  • N,N-diethylaniline sulfate
  • 3-Nitro-N,N-diethylaniline
  • 4-bromo-n,n-diethylaniline
  • 2-bromo-N,N-diethylaniline
  • 1-(3-Chloro-2-fluorophenyl)cyclopentanecarboxylic Acid
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • C15H10ClF3N6O2
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 3-(6-Chloro-pyrimidin-4-ylsulfanylmethyl)-piperidine-1-carboxylic acid tert-butyl ester
  • (E)-3-(2-Chloropyridin-4-yl)-N-[2-(5-methylfuran-2-yl)-2-pyrrolidin-1-ylethyl]prop-2-enamide
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 5-nitro-2-((piperidin-3-ylmethyl)sulfinyl)-1H-benzo[d]imidazole hydrochloride
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol