griseochelin

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Names

[ CAS No. ]:
91920-88-6

[ Name ]:
griseochelin

[Synonym ]:
zincophorin
Zinchophorine

Chemical & Physical Properties

[ Density]:
1.047g/cm3

[ Boiling Point ]:
712.6ºC at 760 mmHg

[ Molecular Formula ]:
C33H60O7

[ Molecular Weight ]:
568.82500

[ Flash Point ]:
214.6ºC

[ Exact Mass ]:
568.43400

[ PSA ]:
127.45000

[ LogP ]:
5.59770

[ Index of Refraction ]:
1.507

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UP6130000
CHEMICAL NAME :
2H-Pyran-2-acetic acid, tetrahydro-alpha,5-dimethyl-6-(2,4,6,12-tetrahydroxy- 1,3,5,11,13,15- hexamethyl-9,13-octadecadienyl)-
CAS REGISTRY NUMBER :
91920-88-6
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C33-H60-O7
MOLECULAR WEIGHT :
568.93

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JANTAJ Journal of Antibiotics. (Japan Antibiotics Research Assoc., 2-20-8 Kamiosaki, Shinagawa-ku, Tokyo, 141, Japan) V.2-5, 1948-52; V.21- 1968- Volume(issue)/page/year: 37,836,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JANTAJ Journal of Antibiotics. (Japan Antibiotics Research Assoc., 2-20-8 Kamiosaki, Shinagawa-ku, Tokyo, 141, Japan) V.2-5, 1948-52; V.21- 1968- Volume(issue)/page/year: 37,836,1984

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ((2S,3R)-3-((R)-1-((triisopropylsilyl)oxy)propan-2-yl)oxiran-2-yl)methanol
  • (3S,6S)-6-[(1R)-2-triisopropylsilyloxy-1-methylethyl]-3-methyltetrahydro-2H-pyran-2-one
  • (S)-(4,4-dibromo-2-methylbut-3-enyloxy)triisopropylsilane
  • (R)-2-((2S,5S,6S)-6-((S,E)-5-(benzyloxy)pent-3-en-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)propan-1-ol
  • ((2R,3R)-3-((R)-1-((2S,3S,6S)-3-methyl-6-((R)-1-((triisopropylsilyl)oxy)propan-2-yl)tetrahydro-2H-pyran-2-yl)ethyl)oxiran-2-yl)methanol

DownStream

Related Compounds

  • Griseochelin methyl ester
  • 3-tert-butyl-6-[4-({4H,5H,6H-cyclopenta[d][1,3]thiazol-2-yl}methyl)piperazin-1-yl]pyridazine
  • 3-Bromo-4-{[1-(5-cyclopropyl-1,3,4-thiadiazol-2-yl)pyrrolidin-3-yl]oxy}pyridine
  • 2-{3-[(3-Bromopyridin-4-yl)oxy]pyrrolidin-1-yl}-5-chloropyrimidine
  • 2-({1-[(4,5-dimethyl-4H-1,2,4-triazol-3-yl)methyl]piperidin-4-yl}oxy)-5-ethylpyrimidine
  • 4-(3-Cyclopropyl-1,2,4-thiadiazol-5-yl)-1-(2-methoxypyridin-4-yl)piperazin-2-one
  • 5-bromo-2-({1-[(1-methyl-1H-pyrazol-4-yl)methyl]piperidin-3-yl}methoxy)pyrimidine
  • 5-ethyl-2-({1-[(1-methyl-1H-1,2,4-triazol-5-yl)methyl]piperidin-4-yl}oxy)pyrimidine
  • 2-({1-[(4-Methyl-1,3-thiazol-5-yl)methyl]piperidin-3-yl}methoxy)pyridine-4-carbonitrile
  • 3-[3-(3-Bromopyridin-4-yl)oxypyrrolidin-1-yl]pyrazine-2-carbonitrile
  • 5-Ethyl-2-({1-[(1,3-oxazol-4-yl)methyl]piperidin-4-yl}oxy)pyrimidine
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