o-Acetoacetanisidide

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Names

[ CAS No. ]:
92-15-9

[ Name ]:
o-Acetoacetanisidide

[Synonym ]:
2'-acetoacetanisidide
2'-methoxyacetoacetanilide
Butanamide, N-(2-methoxyphenyl)-3-oxo-
2-acetoacetylamino-anisol
aceto-acetyl-amino-2-methoxy-benzene
Acetoacetanisidide
1-acetoacetylamino-2-methoxybenzene
1V1VMR BO1
Acetoacetyl-o-anisidide
AAOA
acetoacetamino-2-methoxybenzene
Acetoacet-o-anisidin
Acetacet-O-anisidine
o-Acetoacetanisidide
o-Acetoacetanisidine
N-(2-Methoxyphenyl)-3-oxobutanamide
MFCD00008781
Acetoacetic acid o-anisidide
EINECS 202-131-0
Acetoacet-o-anisidide

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
372.9±22.0 °C at 760 mmHg

[ Melting Point ]:
85-87 °C(lit.)

[ Molecular Formula ]:
C11H13NO3

[ Molecular Weight ]:
207.226

[ Flash Point ]:
179.3±22.3 °C

[ Exact Mass ]:
207.089539

[ PSA ]:
55.40000

[ LogP ]:
0.75

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.553

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BZ5600000
CHEMICAL NAME :
o-Anisidine, acetoacetyl-
CAS REGISTRY NUMBER :
92-15-9
BEILSTEIN REFERENCE NO. :
1459707
LAST UPDATED :
199710
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C11-H13-N-O3
MOLECULAR WEIGHT :
207.25
WISWESSER LINE NOTATION :
1V1VMR BO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,705,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,705,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - muscle weakness Skin and Appendages - hair
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570984 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
9926 mg/kg/14D-C
TOXIC EFFECTS :
Blood - macrocytosis
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570984

Safety Information

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22

[ WGK Germany ]:
1

[ RTECS ]:
BZ5600000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Ethyl acetoacetate
  • 2-Anisidine
  • 2,2,6-Trimethyl-4H-1,3-dioxin-4-one
  • but-1-ene-1,3-dione
  • Diketene
  • Methyl acetoacetate

DownStream

  • 2-Anisidine
  • Pigment Yellow 74
  • Pigment Yellow 65
  • 2-chloro-N-(2-methoxyphenyl)-3-oxobutanamide
  • N,1-bis(2-methoxyphenyl)-2,6-dimethyl-4-oxopyridine-3-carboxamide
  • 2(1H)-Quinolinone,8-methoxy-4-methyl-6-nitro-

Related Compounds

  • O-ACETOACETANISIDIDE
  • 5'-Methyl-o-acetoacetanisidide
  • O-butyl butoxycarbothioylsulfanylmethoxymethylsulfanylmethanethioate
  • O-methyl-N,N-dimethylamidophosphorothiochloridate
  • [o-[5-[2-hydroxy-5-[(m-sulphamoylphenyl)sulphamoyl]phenyl]-3-phenyl-1-formazano]benzoato(2-)]copper
  • o-Nitrobenzyl-5 tetrahydro-5,6,7,7a 4H-thieno(3,2-c)pyridinone-2 oxala te [French]