Methanediamine,1-phenyl-N,N'-bis(phenylmethylene)-

Names

[ CAS No. ]:
92-29-5

[ Name ]:
Methanediamine,1-phenyl-N,N'-bis(phenylmethylene)-

[Synonym ]:
MFCD00022039
(E)-N-[[(E)-benzylideneamino]-phenylmethyl]-1-phenylmethanimine
EINECS 202-144-1

Chemical & Physical Properties

[ Density]:
1.01 g/cm3

[ Boiling Point ]:
422.6ºC at 760 mmHg

[ Melting Point ]:
102-105ºC(lit.)

[ Molecular Formula ]:
C₂₁H₁₈N₂

[ Molecular Weight ]:
298.38100

[ Flash Point ]:
202ºC

[ Exact Mass ]:
298.14700

[ PSA ]:
24.72000

[ LogP ]:
4.92340

[ Index of Refraction ]:
1.578

[ Storage condition ]:
2-8℃

MSDS

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301

[ Precautionary Statements ]:
P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R25

[ Safety Phrases ]:
45-22-24-25

[ RIDADR ]:
UN 2811 6.1/PG 3

[ HS Code ]:
2921590090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Benzaldehyde
benzyl azide
1N1&VR
Hexamethyldisilazane
Methanediol, 1-phenyl-,1,1-diacetate
2-Benzyl-3-phenyloxaziridine
(R)-2-benzyl-3-(4-chlorophenyl)-1,2-oxaziridine
(E)-2-benzyl-3-(4-methoxyphenyl)oxoaziridine
2-benzyl-3-(4-nitro-phenyl)-oxaziridine

DownStream

Benzaldehyde dimethyl acetal
N-chloro-1-phenylmethanimine
s-Triazine, 2,4,6-triphenyl- (8CI)
Benzamide
Benzylamine
Benzenemethanamine,N-(phenylmethylene)-
Toluene
Dibenzylamine
Benzamide,N-(diphenylmethyl)-
lophine

Customs

[ HS Code ]: 2921590090

[ Summary ]:
2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

A simplified synthesis of (±)-1, 2-diphenyl-1, 2-diaminoethane (1) from benzaldehyde and ammonia. Revision of the structures of the long-known intermediates “hydrobenzamide” and “amarine”. Corey EJ and Kühnle FNM.

Tetrahedron Lett. 38(50) , 8631-34, (1997)

Synthesis and solution studies of Cu (II) complexes with pyridine derivatives of iminobisphosphonic acids. Goldeman W, et al.

Inorganica Chim. Acta 365(1) , 391-99, (2011)

An effective method to prepare imines from aldehyde, bromide/epoxide, and aqueous ammonia.

J. Org. Chem. 76(9) , 3511-4, (2011)

A three-component reaction of aldehydes, alkyl bromides, and ammonia to form imines was studied. Aqueous ammonia was applied as the nitrogen source and solvent in the reaction. For the aromatic aldehy...

Methanediamine,1-phenyl-N,N'-bis(phenylmethylene)-,(E,E)
1-phenyl-N,N-bis(1,3-thiazol-2-yl)methanediamine
N-[5-(benzylideneamino)-1-phenyl-1,2,4-triazol-3-yl]-1-phenylmethanimine
Methanediamine,1-(4-methoxyphenyl)-N,N'-bis[(4-methoxyphenyl)methylene]-
Methanediamine,1-(2-chlorophenyl)-N,N'-bis[(2-chlorophenyl)methylene]-
Methanediamine,1-(4-nitrophenyl)-N,N'-bis[(4-nitrophenyl)methylene]-