4-Bromobiphenyl

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Names

[ CAS No. ]:
92-66-0

[ Name ]:
4-Bromobiphenyl

[Synonym ]:
1-bromo-4-phenylbenzene
1,1'-Biphenyl, 4-bromo-
4-Bromobiphenyl
EINECS 202-176-6
4-Bromo-biphenyl
4-(4'-Bromophenyl)benzene
4-Bromobiphényl
MFCD00000100
4-bromo-1,1'-biphenyl

Chemical & Physical Properties

[ Density]:
0.9327

[ Boiling Point ]:
310 ºC

[ Melting Point ]:
89-92 ºC

[ Molecular Formula ]:
C12H9Br

[ Molecular Weight ]:
233.104

[ Flash Point ]:
143 ºC

[ Exact Mass ]:
231.988754

[ LogP ]:
4.88

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.601

[ Stability ]:
Stable. Incompatible with oxidizing agents.

[ Water Solubility ]:
Insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DV1750100
CHEMICAL NAME :
Biphenyl, 4-bromo-
CAS REGISTRY NUMBER :
92-66-0
LAST UPDATED :
199803
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C12-H9-Br
MOLECULAR WEIGHT :
233.12

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
50 ug/plate
REFERENCE :
BCPCA6 Biochemical Pharmacology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1958- Volume(issue)/page/year: 27,1245,1978

Safety Information

[ Symbol ]:

GHS05, GHS07, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H315-H318-H335-H400

[ Precautionary Statements ]:
P273-P280-P301 + P312 + P330-P305 + P351 + P338 + P310-P391

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S22-S24/25-S37/39-S26

[ RIDADR ]:
UN 3152 9/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
DV1750100

[ Packaging Group ]:
II

[ HS Code ]:
2902909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Bromo-4-iodobenzene
  • Phenylboronic acid
  • 1,4-Dibromobenzene
  • (biphenyl-4-yl)(mesityl)iodonium trifluoromethanesulfonate
  • 4-Bromobenzenediazonium tetrafluoroborate
  • Iodobenzene
  • 4-Bromophenylboronic Acid
  • Sodium tetraphenylborate
  • benzene
  • Tetraphenylphosphonium chloride

DownStream

  • 1,1':4',1'':4'',1''':4''',1''''-Quinquephenyl
  • Methanone,bis([1,1'-biphenyl]-4-yl)-
  • N-Phenyl-4-biphenylamine
  • N-(4-Biphenylyl)-N-phenyl-4-biphenylamine
  • 4-Amino-4'-cyanobiphenyl
  • 4-Biphenylylmethanol
  • 2-(4-Biphenylylcarbonyl)benzoic acid
  • 3-(Trifluoromethyl)-1H-pyrazole-5-carboxamide
  • 4-CYANO-4'-NITRODIPHENYL
  • 2-[1,1-Biphenyl]-4-Yl-1-Ethanol

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Update on biological actions of 1alpha,25(OH)2-vitamin D3 (rapid effects) and 24R,25(OH)2-vitamin D3.

Biochem. Pharmacol. 31(10) , 1849-56, (1982)

All biologic responses to vitamin D are now known to arise as a consequence of the metabolism of this seco-steroid into its two principal biologically active metabolites 1alpha,25(OH)(2)-vitamin D(3) ...

A Taiji-principle-designed magnetic porous C-doped graphitic carbon nitride for environment-friendly solid phase extraction of pollutants from water samples.

J. Chromatogr. A. 1412 , 12-21, (2015)

A new magnetic porous carbon-doped graphitic carbon nitride nanocomposite and experimental strategies were environment-friendly designed for solid phase extraction of brominated flame retardants from ...

Halopicolinic acids, novel products arising through the degradation of chloro- and bromo-biphenyl by Sphingomonas paucimobilis BPSI-3.

Can. J. Microbiol. 42(1) , 66-71, (1996)

Sphingomonas paucimobilis BPSI-3 was previously isolated from a mixed microbial consortium growing on biphenyl as the sole source of carbon and energy. Transformation of 4-chlorobiphenyl (4CBP) was de...


More Articles

Related Compounds

  • 4-Bromobiphenyl
  • 2-Amino-4-bromobiphenyl
  • 2-chloro-4-bromobiphenyl
  • 2-methyl-4-bromobiphenyl
  • 4-Bromobiphenyl-4-yl triflate
  • 4'-methylthio-4-bromobiphenyl
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • 3,4-Dichloro-5-methylphenylacetonitrile