(2H2)Formic acid

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Names

[ CAS No. ]:
920-42-3

[ Name ]:
(2H2)Formic acid

[Synonym ]:
MFCD00037363
Formic acid-d
(H)Formic acid
deuterio deuterioformate
EINECS 213-057-3

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
100.6±9.0 °C at 760 mmHg

[ Melting Point ]:
8.2-8.4ºC(lit.)

[ Molecular Formula ]:
CD2O2

[ Molecular Weight ]:
48.038

[ Flash Point ]:
29.9±13.4 °C

[ Exact Mass ]:
48.018032

[ PSA ]:
37.30000

[ LogP ]:
-0.54

[ Vapour Pressure ]:
36.5±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.342

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
16-23-26-36/37/39-45

[ RIDADR ]:
UN 1779 8

[ WGK Germany ]:
3

Synthetic Route

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Precursor & DownStream

Precursor

  • Oxalic Acid-d2
  • Sodium (2H)formate
  • (2H3)Phosphoric acid
  • Sodium cyanide
  • Oxalic acid
  • Formic Acid
  • Methanol-d4
  • Carbon dioxide

DownStream

  • carbon monoxide
  • Heavy water
  • Methyl (2H)formate
  • Allyl alcohol
  • trimethyl-d8-amine
  • trimethyl-d9-amine
  • (2H5)-2-Propen-1-ol

Articles

Enzymatic synthesis of [4R-2H]NAD (P)H and [4S-2H]NAD(P)H and determination of the stereospecificity of 7 alpha- and 12 alpha hydroxysteroid dehydrogenase.

Biochim. Biophys. Acta 998 , 173, (1989)

The stereospecifically labeled coenzymes [4R-2H]NADH, [4R-2H]NADPH and [4S-2H]NAD(P)H were synthesized enzymatically in high yield and high isotopic purity (greater than or equal to 95%) with 2HCOO2H/...


More Articles

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