diisopropylphosphoramidous dichloride

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Names

[ CAS No. ]:
921-26-6

[ Name ]:
diisopropylphosphoramidous dichloride

[Synonym ]:
dichloro-N,N-diisopropylamino-phosphane
dichloro-N,N-diisopropylaminophosphine
Cl2PN-i-Pr2
Diisopropylphosphoramidous dichloride
MFCD00012236
Diisopropylaminophosphordichloride

Chemical & Physical Properties

[ Density]:
1.096 g/mL at 25ºC(lit.)

[ Boiling Point ]:
209.7ºC at 760 mmHg

[ Molecular Formula ]:
C₆H₁₄Cl₂NP

[ Molecular Weight ]:
202.06200

[ Flash Point ]:
66ºC

[ Exact Mass ]:
201.02400

[ PSA ]:
16.83000

[ LogP ]:
3.80970

[ Index of Refraction ]:
n20/D 1.485(lit.)

[ Storage condition ]:
Hygroscopic, Refrigerator, Under Inert Atmosphere

[ Stability ]:
Moisture Sensitive

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250-H314

[ Supplemental HS ]:
Explosive when dry., Reacts violently with water.

[ Precautionary Statements ]:
P222-P231-P280-P305 + P351 + P338-P310-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
E: Explosive;C: Corrosive;

[ Risk Phrases ]:
R1

[ Safety Phrases ]:
15-26-27-36/37/39-45

[ RIDADR ]:
UN 2846

[ Packaging Group ]:
I

[ Hazard Class ]:
4.2

Synthetic Route

Click to get detail synthetic route

Articles

J. Org. Chem. 59 , 6687, (1994)

Tetrahedron 47 , 2449, (1991)

N,N-diisopropylphosphoramidous dichloride
diisopropylphosphoramidous acid 2-cyanoethyl ester (dimethylpyren-1-yl-silanyl)methyl ester
Disulfur dichloride
Methylphosphonic dichloride
SUBERYLDICHOLINE DICHLORIDE
tetraamminechloronitrosylruthenium dichloride
3,4-dicyclopropyl-1-methyl-4,5-dihydro-1H-1,2,4-triazol-5-one
methyl 2-(3-(4-methylpiperazin-1-yl)propanamido)-5,6-dihydro-4H-cyclopenta[b]thiophene-3-carboxylate dioxalate
2-(4-Fluoro-4'-methoxy-[1,1'-biphenyl]-2-yl)acetic acid
1-[4-(Morpholine-4-carbonyl)piperidin-1-yl]isoquinoline
Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde, 3-phenyl-, (1R,2R,3R,4S)-
L-Alanine, N-methyl-N-[(methyldithio)acetyl]-
N1-Methyl-N1-[[2-(3-pyridinyl)-5-thiazolyl]methyl]-1,2-ethanediamine
4-chloro-3,5-bis(4-fluorophenyl)-1-(2-methylbenzyl)-1H-pyrazole
(S)-8,9-Dichloro-1-methyl-2,3,4,5-tetrahydro-1H-benzo[d]azepine
2,4-Bis(1,1-dimethylethyl)oxazole

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