ETHYLMAGNESIUM BROMIDE

Suppliers

Names

[ CAS No. ]:
925-90-6

[ Name ]:
ETHYLMAGNESIUM BROMIDE

[Synonym ]:
ethylmagnesium bromide
MFCD00000043
EINECS 213-127-3

Chemical & Physical Properties

[ Density]:
1.02 g/mL at 25 °C

[ Boiling Point ]:
34.6°C

[ Melting Point ]:
-116.3°C

[ Molecular Formula ]:
C2H5BrMg

[ Molecular Weight ]:
133.27000

[ Flash Point ]:
<−30 °F

[ Exact Mass ]:
131.94300

[ LogP ]:
1.81950

[ Storage condition ]:
water-free area

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H250-H260-H314

[ Supplemental HS ]:
May form explosive peroxides., Reacts violently with water.

[ Precautionary Statements ]:
P210-P222-P223-P231 + P232-P370 + P378-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F+:Extremelyflammable;Xn:Harmful;C:Corrosive;

[ Risk Phrases ]:
R12;R15;R19;R22;R34

[ Safety Phrases ]:
S16-S26-S36/37/39-S43-S45-S7/8-S27

[ RIDADR ]:
UN 3399 4.3/PG 1

[ WGK Germany ]:
1

[ Packaging Group ]:
I

[ Hazard Class ]:
4.3

[ HS Code ]:
2931900090

Synthetic Route

Precursor & DownStream

Precursor

  • Bromoethane
  • Magnesium
  • Ethyl iodide
  • diethyl-hydrido-germanium; triethylgermanium
  • Di-tert-butyl peroxide
  • MAGNESIUMANTHRACENE TETRAHYDROFURAN COMPLEX
  • Diethyl ether
  • bromo-triethyl-plumbane

DownStream

  • 1-(6-bromopyridin-3-yl)cyclopropan-1-amine
  • Benzenemethanol, a-ethyl-a-methyl-
  • 3,4-dimethyl-3,4-diphenylhexane
  • trimethyl(3-tritert-butylstannylprop-1-ynyl)germane
  • 4-methylpent-2-yne-1,4-diol
  • 1-ETHYLALLYL ACETATE
  • ethylmercury bromide
  • Methyl 4-(1-aminocyclopropyl)benzoate
  • 9-ethyl-10-methyl-9H-acridine
  • 1-(6-methoxypyridin-2-yl)cyclopropan-1-amine

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

New reagent system for attaining high regio- and stereoselectivities in allylic displacement of 4-cyclopentene-1,3-diol monoacetate with aryl- and alkenylmagnesium bromides.

Org. Lett. 7(2) , 183-6, (2005)

[Reaction: see text] Low regioselectivity of RMgBr (R = aryl, alkenyl) in the CuCN-catalyzed reaction with 4-cyclopentene-1,3-diol monoacetate is improved by addition of LiCl or MgCl2 to a similar ext...

Rhodococcus opacus strain PD630 as a new source of high-value single-cell oil? Isolation and characterization of triacylglycerols and other storage lipids.

Microbiology 146 ( Pt 5) , 1143-9, (2000)

The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for ...

Studies of the formation of all-carbon quaternary centres, en route to lyngbyatoxin A. A comparison of phenyl and 7-substituted indole systems.

Org. Biomol. Chem. 2(10) , 1447-55, (2004)

Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carb...


More Articles


Related Compounds

  • METHYLMAGNESIUM BROMIDE
  • d5-ethylmagnesium bromide
  • .D3-ethylmagnesium bromide
  • Ethylmagnesium bromide solution
  • 4-methoxyphenethylmagnesium bromide
  • 4-METHOXYPHENETHYLMAGNESIUM BROMIDE
  • 2-{1-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methoxybutanoyl]piperidin-3-yl}acetic acid
  • 5-{[(tert-butoxy)carbonyl]amino}-4,5,6,7-tetrahydro-1H-indazole-3-carboxylic acid
  • 3-Amino-3-{imidazo[1,2-a]pyridin-2-yl}cyclobutan-1-ol
  • methyl 4-(3-aminoprop-1-en-2-yl)-1-methyl-1H-pyrrole-2-carboxylate
  • 3-(2,6-Dichloro-5-fluoropyridin-3-yl)-3,3-difluoropropanoic acid
  • 2,2-Difluoro-2-[5-fluoro-2-(trifluoromethyl)phenyl]acetic acid
  • 3-(2-Chloro-4,5-difluorophenyl)-3,3-difluoropropanoic acid
  • Diethyl ((6-hydroxybenzo[d]thiazol-2-yl)methyl)phosphonate
  • 3-Amino-1-(3,3-dimethylcyclopentyl)propan-1-one
  • 4-(5-Ethyl-1,3,4-thiadiazol-2-yl)-1-{[3-(propan-2-yl)-1,2,4-oxadiazol-5-yl]methyl}piperidine
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