Acetoacet-o-toluidide

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Names

[ CAS No. ]:
93-68-5

[ Name ]:
Acetoacet-o-toluidide

[Synonym ]:
acetoacetamino-2-methylbenzene
Acetoacet-O-toludide
EINECS 202-267-0
3-Oxo-N-(2,4-methylphenyl)butanamide
2'-Methylacetoacetanilide
N-(2-Methylphenyl)-3-oxobutanamide
O-Acetoacetoluidide
acetoacetyl o-methylaniline
O-ACETOACETOTOLUIDIDE
ACETO ACET O TOLUIDINE
1V1VMR B1
Butanamide, N-(2-methylphenyl)-3-oxo-
N-(2-methylphenyl)acetoacetamide
2'-acetoacetoluidide
2'-Methylacetoacetan
2'-METHYL-3-PHENYLPROPIOPHENONE
2-acetyl-6-methylacetanilide
N-(o-tolyl)acetoacetic amide
Acetoacet-o-toluidide
AAOT
2-ACETOACETOTOLUIDIDE
MFCD00008782
AcetoAcet-O-Toluilide

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
360.6±25.0 °C at 760 mmHg

[ Melting Point ]:
104-106 °C(lit.)

[ Molecular Formula ]:
C11H13NO2

[ Molecular Weight ]:
191.226

[ Flash Point ]:
143.3±0.0 °C

[ Exact Mass ]:
191.094635

[ PSA ]:
46.17000

[ LogP ]:
1.31

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.560

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AK6550000
CHEMICAL NAME :
o-Acetoacetotoluidide
CAS REGISTRY NUMBER :
93-68-5
BEILSTEIN REFERENCE NO. :
2099098
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C11-H13-N-O2
MOLECULAR WEIGHT :
191.25
WISWESSER LINE NOTATION :
1V1VMR B

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: GN-229B,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: GN-229B,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
>1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: GN-229B,1983

Safety Information

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S36

[ WGK Germany ]:
1

[ RTECS ]:
AK6550000

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • tert-Butyl acetoacetate
  • o-Toluidine
  • Ethyl acetoacetate
  • 2-(bis(ethylthio)methylene)-3-oxo-N-(o-tolyl)butanamide
  • p-Bromoacetylbiphenyl
  • 2-Bromoacetophenone
  • 2-bromo-4'-methylacetophenone
  • 2-Bromo-4'-chloroacetophenone
  • 2-[bis(benzylthio)methylene]-3-oxo-N-o-tolylbutanamide
  • 1-Bromobutane

DownStream

  • 2-CHLORO-4,8-DIMETHYLQUINOLINE
  • Acetamide,2,2-dichloro-N-(2-methylphenyl)-
  • 2-HYDROXYIMINO-3-OXO-N-O-TOLYL-BUTYRAMIDE
  • 1-Isocyanato-2-methylbenzene
  • 2(1H)-Quinolinone,4,8-dimethyl-
  • 4,8-dimethylquinoline
  • 4-benzylsulfanyl-4-methylpentan-2-one
  • Ethanone,1-phenyl-2-[(phenylmethyl)thio]-
  • 2,6-dimethyl-4-oxo-N,1-diphenylpyridine-3-carboxamide
  • 2,6-dimethyl-N,1-bis(2-methylphenyl)-4-oxopyridine-3-carboxamide

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • Acetoacet-o-toluidide
  • 2-hydroximinoacetoacet-o-toluidide
  • 2-hydroximinoacetoacet-o-toluidide
  • Acetoacet-o-chloranilide
  • sarcosine o-toluidide
  • (cyclohexylideneacetyl)-o-toluidide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 7-[(2-chlorophenyl)methyl]-3,9-dimethyl-1-propyl-5a,9a,10,10a-tetrahydro-4H-purino[8,7-c][1,2,4]triazine-6,8-dione
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • (R)-N-((2-chlorothiazol-5-yl)methyl)piperidin-3-amine hydrochloride
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine