Glycidyl Methyl Ether

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Names

[ CAS No. ]:
930-37-0

[ Name ]:
Glycidyl Methyl Ether

[Synonym ]:
(Methoxymethyl)oxirane
3-Methoxypropylene oxide
Oxirane, (methoxymethyl)-
Methyl-(2,3-epoxypropyl) Ether
2-(Methoxymethyl)oxirane
Methyl glycidyl ether
Epimethylin
Oxirane, 2-(methoxymethyl)-
Glycidyl Methyl Ether
Propane, 1,2-epoxy-3-methoxy-
1,2-Epoxy-3-methoxypropane
3-Methoxy-1,2-epoxypropane
EINECS 213-216-7
2,3-Epoxypropyl methyl ether

Chemical & Physical Properties

[ Density]:
0.9807 g/cm3 (20 ºC)

[ Boiling Point ]:
113 ºC (760 Torr)

[ Molecular Formula ]:
C4H8O2

[ Molecular Weight ]:
88.105

[ Flash Point ]:
8.1±3.4 °C

[ Exact Mass ]:
88.052429

[ PSA ]:
21.76000

[ LogP ]:
-0.17

[ Vapour Pressure ]:
21.6±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.411

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TZ3530000
CHEMICAL NAME :
Propane, 1,2-epoxy-3-methoxy-
CAS REGISTRY NUMBER :
930-37-0
BEILSTEIN REFERENCE NO. :
0102505
LAST UPDATED :
199806
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C4-H8-O2
MOLECULAR WEIGHT :
88.12
WISWESSER LINE NOTATION :
T3OTJ B1O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
467 uL/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
707 uL/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Skin and Appendages - dermatitis, other (after systemic exposure)

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
DOSE/DURATION :
1250 umol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 249,55,1991

Safety Information

[ Hazard Codes ]:
F+

[ Risk Phrases ]:
10

[ Safety Phrases ]:
S16

[ RIDADR ]:
UN 3271

[ RTECS ]:
TZ3530000

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2910900090

Synthetic Route

Precursor & DownStream

Precursor

  • 2-Propanol,1-chloro-3-methoxy-
  • Epichlorohydrin
  • Methanol
  • Epibromohydrin
  • Sodium Methylate
  • 1,3-Dichloropropane
  • 3-Chloro-1-propanol
  • 3-methoxypropene
  • 2-chloro-3-methoxy-propan-1-ol

DownStream

  • Thiirane,2-(methoxymethyl)-
  • 2-Propanol,1-[(2-hydroxyethyl)amino]-3-methoxy-
  • 1-Methoxyacetone
  • 3-Methoxy-propionaldehyde
  • (R)-3-methoxy-1,2-propanediol
  • (S)-3-methoxy-1,2-propanediol
  • (2S)-2-(Methoxymethyl)oxirane
  • (2R)-2-(Methoxymethyl)oxirane
  • 1-methoxy-3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazol-5-yl]propan-2-ol
  • 1-Methoxy-2-propanol

Customs

[ HS Code ]: 2910900090

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%


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  • EQUILIN METHYL ETHER
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  • linalyl methyl ether
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  • (R)-7-Amino-5-benzyl-5-azaspiro[2.4]heptan-4-one
  • Ethyl 3-oxo-1-thiaspiro[4.5]decane-2-carboxylate
  • Ethyl 3-(3-chloro-2-fluorophenyl)-5-methylisoxazole-4-carboxylate
  • Glycinamide, L-methionyl-N-(2-benzoyl-4-chlorophenyl)-N-methyl-
  • 5-(4-Fluorophenyl)-2-(methylthio)thiazole-4-carboxylic acid