2-CHLORO-N-METHYLANILINE

Suppliers

Names

[ CAS No. ]:
932-32-1

[ Name ]:
2-CHLORO-N-METHYLANILINE

[Synonym ]:
o-chloro-N-methylaniline
2-Cl-N-Me-aniline
2-(Methylamino)chlorobenzene
2-chloro-N-methyl-aniline
(2-chlorophenyl)methylamine
Benzenamine,2-chloro-N-methyl
n1-methyl-2-chloroaniline
N-Methyl-2-chloroaniline
2-chloranyl-N-methyl-aniline
MFCD00045170
2-chloro-N-methylbenzenamine

Chemical & Physical Properties

[ Density]:
1.15 g/mL at 25 °C(lit.)

[ Boiling Point ]:
218 °C(lit.)

[ Melting Point ]:
218 °C (lit.)

[ Molecular Formula ]:
C7H8ClN

[ Molecular Weight ]:
141.59800

[ Flash Point ]:
198 °F

[ Exact Mass ]:
141.03500

[ PSA ]:
12.03000

[ LogP ]:
2.45470

[ Index of Refraction ]:
n20/D 1.579(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
2810

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

Synthetic Route

Precursor & DownStream

Precursor

  • 2-Chloroaniline
  • methyl iodide
  • Formaldehyde
  • 2-Nitrochlorobenzene
  • N-Methylaniline
  • 2-Bromochlorobenzene
  • methylamine
  • ethyl N-(2-chlorophenyl)methanimidate

DownStream

  • N-(2-chlorophenyl)-N-methylformamide
  • 1-Methylindole-3-acetonitrile
  • 1H-Indole,1,3-dimethyl-
  • 9-Methylcarbazole
  • 2-diphenylphosphanyl-N-methylaniline
  • 1-Methyl-1H-indole-2-carboxylic acid
  • 1,3,3-Trimethyl-2,3-dihydro-1H-indole-2-one
  • (2-Ethylphenyl)methylamine
  • 1,3-DIMETHYLINDOLIN-2-ONE

Articles

Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes. Boebel TA and Hartwig JF.

J. Am. Chem. Soc. 130(24) , 7534-7535, (2008)

Amine‐blocked polyisocyanates. I. Synthesis of novel N‐methylaniline‐blocked polyisocyanates and deblocking studies using hot‐stage fourier transform infrared spectroscopy. Sankar G and Nasar AS.

J. Polym. Sci. A Polym. Chem. 45(8) , 1557-1570, (2007)

Molecular and crystal structures of N-methyl-N-nitro-2-chloroaniline. Prezhdo VV, et al.

Crystallogr. Rep. 46(3) , 389-393, (2001)


More Articles


Related Compounds

  • 2-Chloro-N-methylaniline,HCl
  • 5-Bromo-2-chloro-N-methylaniline
  • N-(2-bromoallyl)-2-chloro-N-methylaniline
  • 2-Chloro-N-(4-fluorobenzyl)-4-Methylaniline
  • 2-Chloro-N-(3-fluorobenzyl)-4-Methylaniline
  • 2-chloro-N-(2-ethoxyethyl)-6-methylaniline
  • 2-{1-[(tert-butoxy)carbonyl]-4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpiperidin-4-yl}acetic acid
  • 2-{8-[(Tert-butoxy)carbonyl]-3-{[(tert-butoxy)carbonyl]amino}-8-azabicyclo[3.2.1]octan-3-yl}acetic acid
  • 3,4-Bis({[(tert-butoxy)carbonyl]amino})-3-(ethoxymethyl)butanoic acid
  • 6-[(tert-butoxy)carbonyl]-8-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-6-azaspiro[3.4]octane-2-carboxylic acid
  • 2-{[(5-Ethylfuran-2-yl)methyl]sulfanyl}-2-methylpropanoic acid
  • 3-{1-[(tert-butoxy)carbonyl]piperidin-4-yl}-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanoic acid
  • 4-{[(tert-butoxy)carbonyl]amino}-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanoic acid
  • 2-(3-{[(Benzyloxy)carbonyl]amino}-6-[(tert-butoxy)carbonyl]-6-azabicyclo[3.2.1]octan-3-yl)acetic acid
  • 4-(2-Carbamoylazetidin-1-yl)-4-oxobutanoic acid
  • 2-(3-{[(Benzyloxy)carbonyl]amino}-8-[(tert-butoxy)carbonyl]-8-azabicyclo[3.2.1]octan-3-yl)acetic acid
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